IGCSE Chemistry 0620 Paper 31, May/June 2026

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Question paper

0620/31 · May/June 2026

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1

The structures of six substances, A to F, are shown in Figure 1.1. Figure 1.1 Answer the following questions about these substances. Each substance may be used once, more than once or not at all.

Figure 1 of 1 for question 1
a(i)

State which substance: is an alkane

[1]
a(ii)

State which substance: is made by fermentation

[1]
a(iii)

State which substance: is made in a fuel cell

[1]
a(iv)

State which substance: has the general formula CnH2n+2

[1]
a(v)

State which substance: is a polymer

[1]
a(vi)

State which substance: is used in photosynthesis.

[1]
b(i)

State which two substances are hydrocarbons.

[2]
b(ii)

State which two substances are used as solvents.

[2]
2

Table 2.1 shows some properties of the halogens. Table 2.1

Figure 1 of 1 for question 2
a(i)

Use the information in Table 2.1 to answer the following questions. Predict the melting point of iodine.

[1]
a(ii)

Use the information in Table 2.1 to answer the following questions. Predict the density of iodine at room temperature and pressure.

[1]
a(iii)

Use the information in Table 2.1 to answer the following questions. Deduce the physical state of bromine at −1 ∘C. Give a reason for your answer. physical state .................................................................................................................... reason ...............................................................................................................................

[2]
a(iv)

Use the information in Table 2.1 to answer the following questions. Predict the physical state of fluorine at room temperature and pressure.

[1]
b(i)

Chlorine, bromine and iodine are all non-metals. Aqueous chlorine reacts with aqueous sodium iodide to produce aqueous iodine and aqueous sodium chloride. State the name of this type of reaction.

[1]
b(ii)

Chlorine, bromine and iodine are all non-metals. Complete the symbol equation for this reaction. Cl2+.....NaI→..........+2NaCl

[2]
b(iii)

Chlorine, bromine and iodine are all non-metals. Explain why aqueous bromine does not react with aqueous sodium chloride.

[1]
b(iv)

Chlorine, bromine and iodine are all non-metals. On Figure 2.1, complete the dot-and-cross diagram for a molecule of bromine. Show outer shell electrons only.

[2]
3

The equation for the reaction of magnesium with dilute hydrochloric acid is shown. Mg(s)+2HCl(aq)→MgCl2(aq)+H2(g)

Figure 1 of 2 for question 3
Figure 2 of 2 for question 3
a

State the meaning of the symbol (aq) in this equation.

[1]
b(i)

A student investigates the reaction of small pieces of magnesium with excess dilute hydrochloric acid. Figure 3.1 shows the total volume of hydrogen gas released as the reaction proceeds. Name the piece of apparatus used to collect and measure the volume of hydrogen gas produced in this reaction.

[1]
b(ii)

Use the graph in Figure 3.1 to determine the total volume of hydrogen gas released in 10 s. total volume of hydrogen gas = .................................................. cm3

[1]
b(iii)

Use the graph in Figure 3.1 to deduce the time taken for the reaction to finish. time = ....................................................... s

[1]
b(iv)

Explain why the reaction finishes.

[1]
b(v)

The student repeats the experiment using the same volume of dilute hydrochloric acid at a higher temperature. Draw a line on the grid in Figure 3.1 to show how the total volume of hydrogen gas released changes over time in this second experiment.

[2]
b(vi)

State how the rate of reaction differs, if at all, when larger pieces of magnesium are used.

[1]
c(i)

The student repeats the experiment and adds 1 g of a solid, insoluble catalyst. State how the rate of reaction differs, if at all, when a catalyst is added.

[1]
c(ii)

The student repeats the experiment and adds 1 g of a solid, insoluble catalyst. Describe how the student can show the catalyst is unchanged at the end of the reaction. In your answer, include how the catalyst is separated from the reaction mixture.

[3]
4

This question is about organic compounds and their reactions.

Figure 1 of 2 for question 4
Figure 2 of 2 for question 4
a(i)

Compound M is unsaturated. Figure 4.1 shows the displayed formula of compound M. On Figure 4.1, draw a circle around the carboxylic acid functional group.

[1]
a(ii)

Deduce the molecular formula of compound M.

[1]
a(iii)

State why compound M is unsaturated.

[1]
b(i)

Outline how petroleum is separated by fractional distillation. In your answer, include: • the property of the fractions which allows them to be separated • a description of how fractional distillation separates the petroleum into fractions.

[4]
b(ii)

Two of the fractions obtained from petroleum are bitumen and fuel oil. State one use of each of these fractions. bitumen ............................................................................................................................. fuel oil ................................................................................................................................

[2]
c(i)

Pentane is a member of the alkane homologous series. Pentane reacts in the same way as ethane. Name the two products of the complete combustion of pentane.

[2]
c(ii)

Pentane is a member of the alkane homologous series. Pentane reacts in the same way as ethane. Identify the type of reaction that takes place when pentane reacts with chlorine. Draw a circle around your chosen answer. addition neutralisation redox substitution

[1]
5

Three states of matter are solid, liquid and gas.

a

State two general properties of a solid. 1 ................................................................................................................................................ 2 ................................................................................................................................................

[2]
b

Complete Table 5.1 to show the separation and arrangement of particles in a solid and a gas. Table 5.1

[4]
c

Draw a line from each statement to the correct change of state.

[2]
d

A sealed gas syringe contains 60 cm3 of oxygen gas. State how the pressure inside the syringe changes when the plunger of the syringe is pushed in and the temperature remains constant.

[1]
6

Cobalt is a metal.

a(i)

State the period number of cobalt in the Periodic Table.

[1]
a(ii)

Deduce the number of electrons, neutrons and protons in the cobalt ion shown. 2759Co2+ number of electrons .......................................................................................................... number of neutrons ........................................................................................................... number of protons .............................................................................................................

[3]
b

Cobalt is a transition metal that forms coloured compounds. State two other properties of transition metals. 1 ................................................................................................................................................ 2 ................................................................................................................................................

[2]
c(i)

Cobalt reacts with oxygen to form cobalt(III) oxide. Complete the symbol equation for this reaction. .....Co+.....O2→2Co2O3

[1]
c(ii)

State if cobalt(III) oxide is an acidic oxide or a basic oxide. Give a reason for your answer.

[1]
d(i)

Another compound of cobalt is cobalt(II) chloride. Molten cobalt(II) chloride is electrolysed using inert graphite electrodes. Define the term electrolysis.

[2]
d(ii)

Name a metal that is used as an inert electrode.

[1]
d(iii)

Name the products formed at each electrode during the electrolysis of molten cobalt(II) chloride, and give the observations at the positive electrode. product at the negative electrode ...................................................................................... product at the positive electrode ....................................................................................... observations at the positive electrode ............................................................................... ...........................................................................................................................................

[3]
e

Cobalt forms a compound with the nitrate ion. The formula of the compound is Co(NO3)2. Complete Table 6.1 to calculate the relative formula mass of Co(NO3)2. Table 6.1 relative formula mass = .........................................................

[2]
7
a

State the percentage of clean, dry air that is nitrogen.

[1]
b(i)

Sulfur dioxide is an air pollutant. State one source of sulfur dioxide in the air.

[1]
b(ii)

State one adverse effect of sulfur dioxide in the air.

[1]
b(iii)

Oxides of nitrogen are also air pollutants. They form acids when they dissolve in water. Choose the pH value that is acidic. Draw a circle around your chosen answer. pH3 pH7 pH10 pH14

[1]
c

Water from natural sources can be polluted with harmful substances. State why sewage and phosphates in river water are harmful. sewage ..................................................................................................................................... ................................................................................................................................................... phosphates ............................................................................................................................... ...................................................................................................................................................

[2]
d(i)

Name the three elements present in an NPK fertiliser.

[1]
d(ii)

Explain why fertilisers are used.

[1]
e

Some fertilisers contain chloride ions. Describe the test to identify aqueous chloride ions. test ............................................................................................................................................ ................................................................................................................................................... observations .............................................................................................................................

[2]

Mark scheme

0620/31 · May/June 2026

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1a(i) · 1 mark

  • 1 mark

    D

1a(ii) · 1 mark

  • 1 mark

    B

1a(iii) · 1 mark

  • 1 mark

    A

1a(iv) · 1 mark

  • 1 mark

    D

1a(v) · 1 mark

  • 1 mark

    E

1a(vi) · 1 mark

  • 1 mark

    A

1b(i) · 2 marks

  • 1 mark

    C

  • 1 mark

    D

1b(ii) · 2 marks

  • 1 mark

    A

  • 1 mark

    B

2a(i) · 1 mark

  • 1 mark

    values between –6 °C and +183 °C (inclusive of these values)

2a(ii) · 1 mark

  • 1 mark

    values between 3.2 and 8.9 (inclusive of these values)

2a(iii) · 2 marks

  • 1 mark

    liquid

  • 1 mark

    –1 °C is lower than the boiling point but higher than the melting point / –1 °C is between the melting point and boiling point / –1 °C is more than –7 °C AND less than +59 °C

2a(iv) · 1 mark

  • 1 mark

    gas

2b(i) · 1 mark

  • 1 mark

    displacement

2b(ii) · 2 marks

  • 1 mark

    2 (NaI)

  • 1 mark

    I 2

2b(iii) · 1 mark

  • 1 mark

    bromine less reactive than chlorine / chlorine more reactive than bromine

2b(iv) · 2 marks

  • 1 mark

    bonding pair of electrons between bromine atoms

  • 1 mark

    6 non-bonding electrons on each bromine atom

3a · 1 mark

  • 1 mark

    aqueous

3b(i) · 1 mark

  • 1 mark

    (gas) syringe

3b(ii) · 1 mark

  • 1 mark

    16 (cm3)

3b(iii) · 1 mark

  • 1 mark

    40 (seconds)

3b(iv) · 1 mark

  • 1 mark

    all of the magnesium has been used up / all of the magnesium has reacted

3b(v) · 2 marks

  • 1 mark

    steeper gradient with line starting at (0,0)

  • 1 mark

    line levels off at 35 cm3 AND not hitting original line before it’s reached 35 cm3 AND before 35 s

3b(vi) · 1 mark

  • 1 mark

    rate slower / more slowly / decrease

3c(i) · 1 mark

  • 1 mark

    rate faster / reaction speeds up / increase

3c(ii) · 3 marks

  • 1 mark

    filtration

  • 1 mark

    dry

  • 1 mark

    weigh the catalyst and the mass will be the same / weigh the catalyst and the mass will be 1 g

4a(i) · 1 mark

  • 1 mark

    circle around COOH group

4a(ii) · 1 mark

  • 1 mark

    C7H10O3

4a(iii) · 1 mark

  • 1 mark

    contains carbon-carbon double bond(s) / contains C=C bond(s)

4b(i) · 4 marks

  • 1 mark

    property: have different boiling points

  • 1 mark

    heat / vaporise / use high temp / temp over 200 °C

  • 1 mark

    temperature gradient (in column) OR (column) cooler at top ora OR low bp at top OR high bp at bottom (of column)

  • 1 mark

    condensing (of gas)

  • 1 mark

    (collection as) liquids

4b(ii) · 2 marks

  • 1 mark

    bitumen: (making) roads

  • 1 mark

    fuel oil: fuel for ships / or home heating

4c(i) · 2 marks

  • 1 mark

    carbon dioxide

  • 1 mark

    water

4c(ii) · 1 mark

  • 1 mark

    substitution

5a · 2 marks

  • 1 mark

    has a definite shape / does not take the shape of the container

  • 1 mark

    has a definite volume / fixed volume

  • 1 mark

    does not spread over surface / does not flow

  • 1 mark

    cannot be compressed

5b · 4 marks

  • 1 mark

    solid: separation of particles: touching / close together

  • 1 mark

    solid: arrangement: regular / fixed pattern

  • 1 mark

    gas: separation of particles: far apart / long way from each other

  • 1 mark

    gas: arrangement: irregular / no (particular) arrangement / random

5c · 2 marks

  • 2 marks

    all three correct = 2 marks, one correct = 1 mark: carbon dioxide gas turns into liquid carbon dioxide: condensing; ice turns into water: melting; liquid nitrogen changes into nitrogen gas: boiling

5d · 1 mark

  • 1 mark

    (pressure) increases

6a(i) · 1 mark

  • 1 mark

    IV / 4

6a(ii) · 3 marks

  • 1 mark

    electrons: 25

  • 1 mark

    neutrons: 32

  • 1 mark

    protons: 27

6b · 2 marks

  • 1 mark

    high densities

  • 1 mark

    high melting point / high boiling point

  • 1 mark

    act as catalysts

6c(i) · 1 mark

  • 1 mark

    4 (Co) and 3 (O2)

6c(ii) · 1 mark

  • 1 mark

    basic because cobalt is a metal

6d(i) · 2 marks

  • 1 mark

    decomposition of an ionic compound (when molten or in aqueous solution)

  • 1 mark

    by the passage of an electric current

6d(ii) · 1 mark

  • 1 mark

    platinum / Pt

6d(iii) · 3 marks

  • 1 mark

    negative electrode: cobalt

  • 1 mark

    positive electrode: chlorine

  • 1 mark

    observations: (yellow-)green vapour

6e · 2 marks

  • 2 marks

    183

7a · 1 mark

  • 1 mark

    78 (%)

7b(i) · 1 mark

  • 1 mark

    combustion of fossil fuels

7b(ii) · 1 mark

  • 1 mark

    acid rain

7b(iii) · 1 mark

  • 1 mark

    pH 3

7c · 2 marks

  • 1 mark

    sewage: (contains microbes) which cause disease

  • 1 mark

    phosphates: (harm to aquatic life by) deoxygenation of water

7d(i) · 1 mark

  • 1 mark

    nitrogen / phosphorus / potassium

7d(ii) · 1 mark

  • 1 mark

    improved plant growth

7e · 2 marks

  • 1 mark

    chloride ion test: (add nitric acid/ acidify) add (aqueous) silver nitrate

  • 1 mark

    observations: white precipitate

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