IGCSE Chemistry 0620 Paper 31, Oct/Nov 2025

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0620/31 · Oct/Nov 2025

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1

Fig. 1.1 shows part of the Periodic Table. Fig. 1.1 Answer the following questions using only the symbols of the elements in Fig. 1.1. Each symbol may be used once, more than once or not at all. Give the symbol of the element that:

Figure 1 of 1 for question 1
a

forms an ion which produces a red colour in a flame test

[1]
b

is present in diamond

[1]
c

forms an ion with a charge of 2–

[1]
d

is extracted from bauxite

[1]
e

is used in electrical wiring because of its good electrical conductivity and ductility.

[1]
2

The symbol for an atom of argon is shown. 1840Ar

a

Complete Table 2.1 to show the number of protons and neutrons in one atom of 1840Ar. Table 2.1

[2]
b(i)

Argon is an unreactive monatomic element. Explain what is meant by the term monatomic.

[1]
b(ii)

Explain why argon is unreactive. Give your answer in terms of electronic configuration.

[1]
c

At room temperature and pressure, argon is a gas. A sample of argon is placed in a sealed syringe with a freely moving plunger. Complete Table 2.2 to show the effect, if any, on the volume of argon when: • the temperature of the argon is increased • the pressure of the argon is increased. Use the words increases, decreases or no change in your answer. Table 2.2

[2]
3
Figure 1 of 1 for question 3
a(i)

Table 3.1 shows the masses of ions, in mg, present in a 1000 cm3 sample of river water. Table 3.1 Answer these questions using the information from Table 3.1. Name the positive ion that has the highest concentration.

[1]
a(ii)

State the formula of the sulfate ion.

[1]
a(iii)

Describe a test to identify the presence of iodide ions, I−, in a sample of water. test .................................................................................................................................... ........................................................................................................................................... observations ......................................................................................................................

[2]
a(iv)

Calculate the mass of nitrate ions, NO3−, in 200 cm3 of river water.

[1]
b

Give the formulae of two ions from Table 3.1 which can be combined with potassium ions to make an NPK fertiliser.

[1]
c

Name two ions from Table 3.1 which lead to deoxygenation of water and damage to aquatic life.

[2]
d

The diagram in Fig. 3.1 shows the apparatus used to separate pure water from the sample of river water. Fig. 3.1 Name the separation method shown in Fig. 3.1.

[1]
4
Figure 1 of 2 for question 4
Figure 2 of 2 for question 4
a

Molecules of compound C are produced by some plants. Fig. 4.1 shows the displayed formula of a molecule of compound C. Fig. 4.1 Deduce the molecular formula of compound C to show the number of atoms of carbon, hydrogen and oxygen.

[1]
b

On Fig. 4.1, draw a circle around the part of the molecule which shows that the molecule is unsaturated.

[1]
c

A different molecule found in plants has the molecular formula C11H14O3. Complete Table 4.1 to calculate the relative molecular mass of C11H14O3. Table 4.1

[2]
d

Petroleum is a mixture of hydrocarbons which can be separated into groups of compounds called fractions. Explain what is meant by the term hydrocarbon.

[1]
e(i)

Fig. 4.2 shows the names of some of the fractions obtained from petroleum using a fractionating column. Fig. 4.2 Using only the fractions shown in Fig. 4.2, name the fraction which contains compounds that: have the lowest boiling point

[1]
e(ii)

have the highest viscosity

[1]
e(iii)

are used for jet fuel.

[1]
f(i)

Table 4.2 shows some properties of compounds found in the naphtha fraction. Table 4.2 A molecule of heptane contains seven carbon atoms. Deduce the molecular formula of heptane.

[1]
f(ii)

Use the information in Table 4.2 to predict the melting point of octane, C8H18.

[1]
g(i)

When heated strongly in the presence of a catalyst, decane reacts to form smaller molecules. Name this type of endothermic reaction.

[1]
g(ii)

Ethene is one of the molecules formed when decane is heated strongly in the presence of a catalyst. Draw the displayed formula of ethene. Show all the atoms and all the bonds.

[2]
h(i)

Ethene is polymerised to form the plastic poly(ethene). Name this type of polymerisation.

[1]
h(ii)

Describe two environmental challenges caused by the disposal of plastics such as poly(ethene). 1 ........................................................................................................................................ ........................................................................................................................................... 2 ........................................................................................................................................ ...........................................................................................................................................

[2]
5

This question is about elements in Group I and in Group VII of the Periodic Table and their compounds.

Figure 1 of 2 for question 5
Figure 2 of 2 for question 5
a

Chlorine is in Group VII of the Periodic Table. Give the colour and state of chlorine at room temperature and pressure. colour ........................................................................................................................................ state ..........................................................................................................................................

[2]
b

State the use of chlorine in the treatment of the domestic water supply.

[1]
c

Iodine is in Group VII of the Periodic Table. Table 5.1 shows the melting point and the boiling point of iodine. Table 5.1 Use the information in Table 5.1 to deduce the physical state of iodine at 195°C. Give a reason for your answer. physical state ............................................................................................................................ reason ....................................................................................................................................... ...................................................................................................................................................

[2]
d

Potassium is an element in Group I of the Periodic Table. Elements in Group I have a low density and relatively low melting and boiling points. State one other physical property of potassium.

[1]
e(i)

When a sample of potassium is added to a large container of cold water, a chemical reaction occurs. Describe what is observed when potassium is added to water.

[3]
e(ii)

The word equation for the reaction of potassium with water is shown. potassium + water → potassium hydroxide + hydrogen Describe a test for hydrogen. test .................................................................................................................................... observations ......................................................................................................................

[1]
f

Potassium reacts with oxygen to form potassium oxide, K2O. Complete the symbol equation for this reaction. ...... K + .................... →2K2O

[2]
g

Solid potassium oxide, K2O, dissolves in water to form an alkali. Choose the pH value of the solution formed when solid potassium oxide is dissolved in water. Draw a circle around your chosen answer. pH 1 pH 5 pH 7 pH 12

[1]
h

Potassium reacts with chlorine to form the ionic compound potassium chloride. Complete the dot-and-cross diagram in Fig. 5.1 for potassium chloride to show: • the electronic configuration for each ion • the charge on each ion. Fig. 5.1

[3]
6

This question is about metals.

a(i)

Iron is extracted from its ore using carbon (coke) and calcium carbonate in a blast furnace. Give two reasons why carbon is used in a blast furnace. 1 ........................................................................................................................................ 2 ........................................................................................................................................

[2]
a(ii)

Slag is a waste product of this extraction. Describe how slag is produced.

[2]
a(iii)

Iron ore contains iron(III) oxide. The equation for the extraction of iron from iron(III) oxide is shown. Fe2O3+3CO→2Fe+3CO2 Explain how this equation shows that carbon monoxide is oxidised.

[1]
b(i)

Pure iron is less useful than its alloys such as stainless steel. Name two metals most commonly used in stainless steel, other than iron. 1 ........................................................................................................................................ 2 ........................................................................................................................................

[2]
b(ii)

State one use of stainless steel.

[1]
c(i)

Table 6.1 shows the observations when four different metals are added separately to dilute ethanoic acid. Table 6.1 Put the four metals in order of their reactivity. Put the least reactive metal first.

[2]
c(ii)

Complete the word equation for the reaction of calcium with ethanoic acid. calcium + ethanoic acid → .................... + ....................

[2]
7

Fig. 7.1 shows the apparatus used to electrolyse dilute sulfuric acid using inert electrodes. Fig. 7.1

Figure 1 of 2 for question 7
Figure 2 of 2 for question 7
a

State what is meant by the term electrolysis.

[2]
b

Label the cathode in Fig. 7.1.

[1]
c

Name one product formed at the anode.

[1]
d(i)

The inert electrodes used are made of graphite. Explain what is meant by the term inert.

[1]
d(ii)

State one other use for graphite.

[1]
e(i)

Excess solid copper(II) carbonate is added to dilute sulfuric acid. Aqueous copper(II) sulfate, water and carbon dioxide gas are produced. State with a reason if this is a chemical or a physical change.

[1]
e(ii)

Name a method to remove the excess copper(II) carbonate from the mixture.

[1]
e(iii)

Name one other substance which can be added to dilute sulfuric acid to form aqueous copper(II) sulfate.

[1]
f

Copper(II) sulfate, CuSO4, exists in different forms. Draw one line from each form of copper(II) sulfate to its description. form of copper(II) sulfate description aqueous CuSO4 solid CuSO4 chemically combined with water hydrated CuSO4 CuSO4 dissolved in water anhydrous CuSO4 solid CuSO4 containing no water

[2]
8

A student investigates the reaction of small pieces of magnesium with excess dilute hydrochloric acid. Mg+2HCl→MgCl2+H2 Fig. 8.1 shows the total volume of hydrogen gas, H2, produced as the reaction proceeds. Fig. 8.1

Figure 1 of 2 for question 8
Figure 2 of 2 for question 8
a

Use Fig. 8.1 to deduce the time taken for the reaction to finish.

[1]
b(i)

The reaction is repeated using larger pieces of magnesium of the same total mass. All other conditions stay the same. State the effect, if any, on: the time taken for the reaction to finish

[1]
b(ii)

the total volume of H2 produced when the reaction is complete.

[1]
c

Fig. 8.2 shows the reaction pathway diagram for the reaction of magnesium with dilute hydrochloric acid. Fig. 8.2 Deduce the type of energy change shown in the diagram in Fig. 8.2. Explain your answer.

[2]

Mark scheme

0620/31 · Oct/Nov 2025

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1a · 1 mark

  • 1 mark

    Li

1b · 1 mark

  • 1 mark

    C

1c · 1 mark

  • 1 mark

    S

1d · 1 mark

  • 1 mark

    Al

1e · 1 mark

  • 1 mark

    Cu / Al

2a · 2 marks

  • 1 mark

    number of protons: 18

  • 1 mark

    number of neutrons: 22

2b(i) · 1 mark

  • 1 mark

    (contains only) one atom

2b(ii) · 1 mark

  • 1 mark

    (its atom has) a full outer shell / the outer shell contains 8 electrons

2c · 2 marks

  • 1 mark

    temperature is increased: increases

  • 1 mark

    pressure is increased: decreases

3a(i) · 1 mark

  • 1 mark

    sodium

3a(ii) · 1 mark

  • 1 mark

    SO4^2–

3a(iii) · 2 marks

  • 1 mark

    (dilute nitric acid and aqueous) silver nitrate

  • 1 mark

    yellow precipitate

3a(iv) · 1 mark

  • 1 mark

    1.9 (mg)

3b · 1 mark

  • 1 mark

    PO4^3– AND NH4^+ OR PO4^3– AND NO3^–

3c · 2 marks

  • 1 mark

    nitrate

  • 1 mark

    phosphate

3d · 1 mark

  • 1 mark

    distillation

4a · 1 mark

  • 1 mark

    C10H16O2

4b · 1 mark

  • 1 mark

    C=C circled

4c · 2 marks

  • 2 marks

    194

4d · 1 mark

  • 1 mark

    (compound) which contains carbon and hydrogen only

4e(i) · 1 mark

  • 1 mark

    gasoline / petrol

4e(ii) · 1 mark

  • 1 mark

    lubricating oil

4e(iii) · 1 mark

  • 1 mark

    kerosene / paraffin

4f(i) · 1 mark

  • 1 mark

    C7H16

4f(ii) · 1 mark

  • 1 mark

    any value –55 to –89 (°C) inclusive

4g(i) · 1 mark

  • 1 mark

    cracking

4g(ii) · 2 marks

  • 1 mark

    C2H4 formula

  • 1 mark

    A correct displayed formula and showing C=C

4h(i) · 1 mark

  • 1 mark

    addition

4h(ii) · 2 marks

  • 1 mark

    fills landfill

  • 1 mark

    accumulates in oceans

  • 1 mark

    forms toxic / acidic gases on burning

5a · 2 marks

  • 1 mark

    (pale) yellow-green

  • 1 mark

    gas

5b · 1 mark

  • 1 mark

    kills microbes

5c · 2 marks

  • 1 mark

    gas

  • 1 mark

    (temperature) is above the boiling point (of iodine)

5d · 1 mark

  • 1 mark

    electrical conductor / thermal conductor / malleable / ductile

5e(i) · 3 marks

  • 1 mark

    moves

  • 1 mark

    floats / (moves) on the surface

  • 1 mark

    melts / turns into sphere/ball

  • 1 mark

    effervescence/fizzing/bubbles

  • 1 mark

    pops / explodes

  • 1 mark

    (lilac) flame

  • 1 mark

    solid gets smaller / disappears

  • 1 mark

    temperature increases / heat produced

5e(ii) · 1 mark

  • 1 mark

    test: lighted splint / flame and observations: pops

5f · 2 marks

  • 2 marks

    4K + O2 → 2K2O

5g · 1 mark

  • 1 mark

    pH 12 circled

5h · 3 marks

  • 1 mark

    K+ ion correct

  • 1 mark

    Cl– ion correct

  • 1 mark

    both charges correct

6a(i) · 2 marks

  • 1 mark

    to heat the furnace

  • 1 mark

    to produce carbon dioxide

6a(ii) · 2 marks

  • 1 mark

    thermal decomposition of calcium carbonate/limestone to produce calcium oxide

  • 1 mark

    calcium oxide combines with silicon(IV) oxide to form slag

6a(iii) · 1 mark

  • 1 mark

    carbon monoxide gains oxygen

6b(i) · 2 marks

  • 1 mark

    nickel / Ni

  • 1 mark

    chromium / Cr

6b(ii) · 1 mark

  • 1 mark

    cutlery

6c(i) · 2 marks

  • 2 marks

    Ti → Zn → Mg → Ca

6c(ii) · 2 marks

  • 1 mark

    calcium ethanoate

  • 1 mark

    hydrogen

7a · 2 marks

  • 1 mark

    the decomposition of an ionic compound (when molten or in aqueous solution)

  • 1 mark

    by the passage of an electric current

7b · 1 mark

  • 1 mark

    negative electrode labelled

7c · 1 mark

  • 1 mark

    oxygen

7d(i) · 1 mark

  • 1 mark

    unreactive / does not react

7d(ii) · 1 mark

  • 1 mark

    lubricant

7e(i) · 1 mark

  • 1 mark

    chemical change AND new substances are made

7e(ii) · 1 mark

  • 1 mark

    filtration

7e(iii) · 1 mark

  • 1 mark

    copper oxide / copper hydroxide

7f · 2 marks

  • 1 mark

    aqueous CuSO4 to CuSO4 dissolved in water

  • 1 mark

    hydrated CuSO4 to solid CuSO4 chemically combined with water AND anhydrous CuSO4 to solid CuSO4 containing no water

8a · 1 mark

  • 1 mark

    119 (s)

8b(i) · 1 mark

  • 1 mark

    increases / more time

8b(ii) · 1 mark

  • 1 mark

    no change

8c · 2 marks

  • 1 mark

    exothermic

  • 1 mark

    energy level of products below that of reactants

Questions

  1. 1
    Question 15 marks
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  2. 2
    Question 26 marks
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  3. 3
    Question 39 marks
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  4. 4
    Question 416 marks
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  5. 5
    Question 516 marks
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  6. 6
    Question 612 marks
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  7. 7
    Question 711 marks
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  8. 8
    Question 85 marks
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