O Level Chemistry 5070 Paper 22, Oct/Nov 2025

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5070/22 · Oct/Nov 2025

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1

Choose from the following compounds to answer the questions. compound A CH3OH compound B HCOOH compound C CH3—CH2OH compound D CH3—COOCH3 compound E H2C—CH2/H2C—CH2 compound F CH3—CH2—CH2—CH3 compound G CH3—CH2—CH=CH2 compound H CH3—CH2—CH2—COOH Each compound can be used once, more than once or not at all.

a(i)

State which compound: is methanoic acid

[1]
a(ii)

State which compound: is manufactured by the hydration of ethene

[1]
a(iii)

State which compound: has an empirical formula of C2H4O

[1]
a(iv)

State which compound: is used to make an addition polymer

[1]
a(v)

State which compound: is an ester.

[1]
b

State which two compounds are structural isomers of one another.

[1]
2

A sample of titanium found on an asteroid contains four isotopes. Table 2.1 shows the percentage abundances of these four isotopes. Table 2.1

isotopepercentage abundance
2246Ti9
2247Ti7
2248Ti75
2249Ti9
a

Describe one difference between the isotopes 2246Ti and 2247Ti.

[1]
b

Explain why all the isotopes of titanium have the same chemical properties.

[1]
c

Show by calculation that the relative atomic mass of titanium for this sample is 47.84.

[2]
3

The equation for the reaction between aluminium and dilute hydrochloric acid is shown. 2Al(s)+6HCl(aq)→2AlCl3(aq)+3H2(g)

Figure 1 of 2 for question 3
Figure 2 of 2 for question 3
a(i)

Fig. 3.1 shows the reaction pathway diagram for this reaction. Identify the energy changes labelled A and B. energy change A energy change B

[2]
a(ii)

Use the reaction pathway diagram to explain why the reaction is exothermic.

[1]
b

Describe a chemical test for hydrogen. test observation if hydrogen present

[1]
c

A sample of aluminium reacts completely with dilute hydrochloric acid. A total volume of 366 cm3 of hydrogen, measured at r.t.p., is produced. Calculate the mass of the sample of aluminium. Give your answer to two significant figures. mass of aluminium = ...................................................... g

[3]
4

Fluorine, chlorine, bromine and iodine are elements in Group VII.

a(i)

Fluorine has a low boiling point. It is a gas at room temperature. Describe the arrangement and motion of molecules in fluorine gas.

[2]
a(ii)

Explain why fluorine is a gas at room temperature. Use ideas about structure and bonding.

[1]
b(i)

Bromine reacts with lithium to make the ionic compound lithium bromide. Suggest two physical properties of lithium bromide. 1 2

[2]
b(ii)

Construct the ionic half-equation to show the formation of lithium ions from lithium atoms.

[1]
b(iii)

Construct the ionic half-equation to show the formation of bromide ions from bromine molecules.

[1]
c

Chlorine gas is bubbled into aqueous lithium bromide. A reaction takes place. Name the two products of this reaction.

[1]
5

Nickel is a transition element.

a

One of the properties of nickel is that it is a catalyst. State a reaction that uses nickel as a catalyst.

[1]
b

State one other chemical property of nickel that is typical of a transition element.

[1]
c(i)

The physical properties of nickel and its alloys can be explained using ideas about structure and bonding. Explain why nickel is malleable.

[1]
c(ii)

Nickel and other elements are added to iron to make the alloy stainless steel. Explain why stainless steel is harder than either pure nickel or pure iron. Include a labelled diagram in your answer.

[2]
c(iii)

Stainless steel is used to make cutlery because it is hard and strong. State one other property that makes stainless steel suitable to make cutlery.

[1]
d

Compound X contains nickel, hydrogen and oxygen only. X contains 2.2% by mass of hydrogen and 34.5% by mass of oxygen. Calculate the empirical formula of compound X. empirical formula =

[3]
e

The equation for the reversible reaction between carbon monoxide and nickel is shown. 4CO(g)+Ni(s)⇌Ni(CO)4(g) The forward reaction is exothermic. The reversible reaction is allowed to reach equilibrium in a closed system. Predict and explain the effect of increasing the pressure on the position of equilibrium. The temperature remains constant. prediction explanation

[2]
6

This question is about the covalent compound hydrogen peroxide. Fig. 6.1 shows the displayed formula of hydrogen peroxide. H−O−O−H Fig. 6.1

Figure 1 of 1 for question 6
a

Draw the dot-and-cross diagram to show the electronic arrangement in a molecule of hydrogen peroxide. Only draw the outer shell electrons of oxygen and hydrogen.

[2]
b(i)

A sample of hydrogen peroxide has a mass of 0.170 g. Calculate the number of molecules of hydrogen peroxide in this sample. One mole of hydrogen peroxide contains 6.02×1023 molecules. number of molecules =

[2]
b(ii)

Calculate the total number of atoms in this sample of hydrogen peroxide. number of atoms =

[1]
c

When aqueous hydrogen peroxide reacts with acidified aqueous potassium manganate(VII) there is a colour change from purple to colourless. When aqueous hydrogen peroxide reacts with aqueous potassium iodide there is a colour change from colourless to brown. Explain what these observations indicate about the chemical properties of aqueous hydrogen peroxide.

[2]
d

Barium peroxide reacts with cold dilute sulfuric acid to produce hydrogen peroxide. Barium peroxide contains the ions Ba2+ and O22− only. Deduce the formula of barium peroxide.

[1]
e(i)

The equation for the decomposition of aqueous hydrogen peroxide is shown. 2H2O2(aq)→2H2O(l)+O2(g) The rate of decomposition increases as the temperature of the aqueous hydrogen peroxide increases. Explain why.

[2]
e(ii)

Manganese(IV) oxide is a catalyst for the decomposition of aqueous hydrogen peroxide. Describe how a catalyst increases the rate of reaction.

[1]
7

PET is a polyester. It is a condensation polymer. Fig. 7.1 shows the two monomers needed to make PET.

Figure 1 of 2 for question 7
Figure 2 of 2 for question 7
a

Name the two types of monomer shown in Fig. 7.1. 1 2

[2]
b(i)

The two monomers react to make PET and a small molecule. Name the small molecule.

[1]
b(ii)

Draw the structure of PET. Your structure should show two repeat units.

[2]
b(iii)

State two environmental challenges caused by the disposal of plastics made of PET. 1 2

[2]
c

Name one condensation polymer that is a polyamide.

[1]
8

Fig. 8.1 shows the displayed formula of an unsaturated carboxylic acid, X.

Figure 1 of 1 for question 8
a

Explain why X is unsaturated.

[1]
b

Describe the observations when X reacts with aqueous bromine.

[2]
c

X is a weak acid. Describe the meaning of the term weak in weak acid.

[1]
d

X reacts with aqueous sodium carbonate. Name the gas formed in this reaction.

[1]
e

Describe how an ester is prepared from X.

[2]
f(i)

Ethanoic acid is a saturated carboxylic acid. Describe how ethanoic acid is made from ethanol.

[1]
f(ii)

Dilute ethanoic acid reacts with aqueous sodium hydroxide. Name the two products of this reaction.

[1]
9

Hydrated zinc chloride is a white solid.

a

State the meaning of the term hydrated.

[1]
b

Aqueous ammonia is added dropwise until in excess to a small volume of aqueous zinc chloride. Describe the observations during this addition.

[2]
c

Describe the observations when aqueous silver nitrate is added to aqueous zinc chloride.

[1]
d

Dilute and concentrated aqueous zinc chloride are electrolysed separately using carbon electrodes. Complete Table 9.1. Table 9.1

dilute aqueous zinc chlorideconcentrated aqueous zinc chloride
product at anode
product at cathode
[4]
e

Explain why aqueous zinc chloride conducts electricity but solid zinc chloride does not conduct electricity.

[1]
10

Water is an important part of the environment.

a(i)

Rivers and lakes are natural sources of water. Name one substance in river water that may be harmful. Explain why this substance may be harmful. substance explanation

[1]
a(ii)

Name one substance in river water that is beneficial. Explain why this substance is beneficial. substance explanation

[1]
b

Describe the three processes involved in the treatment of water for the domestic water supply. State the reason why each process is used. process 1 reason process 2 reason process 3 reason

[3]
c

Describe a qualitative chemical test to show the presence of water. chemical test observation

[1]
d

Explain how the purity of water is tested by measuring its boiling point.

[1]

Mark scheme

5070/22 · Oct/Nov 2025

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1a(i) · 1 mark

  • 1 mark

    B

1a(ii) · 1 mark

  • 1 mark

    C

1a(iii) · 1 mark

  • 1 mark

    H

1a(iv) · 1 mark

  • 1 mark

    G

1a(v) · 1 mark

  • 1 mark

    D

1b · 1 mark

  • 1 mark

    E and G

2a · 1 mark

  • 1 mark

    different number of neutrons / different mass number / different nucleon number

2b · 1 mark

  • 1 mark

    same electronic configuration

2c · 2 marks

  • 1 mark

    correct numerator

  • 1 mark

    correct denominator

3a(i) · 2 marks

  • 1 mark

    A activation (energy) / Ea

  • 1 mark

    B enthalpy (change) / ΔH

3a(ii) · 1 mark

  • 1 mark

    product level below reactant level

3b · 1 mark

  • 1 mark

    ‘pops’ with a lighted splint

3c · 3 marks

  • 1 mark

    (moles of hydrogen =) 366 / 24000 OR 0.01525

  • 1 mark

    (moles of Al =) 0.01525 × 0.67 OR 0.01017

  • 1 mark

    mass of Al = 0.27

4a(i) · 2 marks

  • M1

    random (arrangement)

  • M2

    (molecules are spread) far apart

  • M3

    (molecules are) moving (very) fast

  • M4

    random (motion)

4a(ii) · 1 mark

  • 1 mark

    weak intermolecular forces

4b(i) · 2 marks

  • 1 mark

    high melting point / high boiling point

  • 1 mark

    conducts electricity in (aqueous) solution

4b(ii) · 1 mark

  • 1 mark

    Li → Li+ + e−

4b(iii) · 1 mark

  • 1 mark

    Br2 + 2e− → 2Br−

4c · 1 mark

  • 1 mark

    lithium chloride and bromine

5a · 1 mark

  • 1 mark

    reaction of a (named) alkene with hydrogen

5b · 1 mark

  • 1 mark

    more than one oxidation state (in compounds)

5c(i) · 1 mark

  • 1 mark

    layers of (metal) ions can slide (over one another)

5c(ii) · 2 marks

  • M1

    different sized (metal) ions

  • M2

    so layers (of metal ions) cannot slide (easily)

5c(iii) · 1 mark

  • 1 mark

    resistant to rusting

5d · 3 marks

  • 1 mark

    nickel percentage

  • 1 mark

    correct number of moles

  • 1 mark

    empirical formula NiH2O2

5e · 2 marks

  • M1

    (position of equilibrium) moves to the right

  • M2

    because more moles of gas on reactant side / fewer moles of gas on product side / greater volume of gas on reactant side / smaller volume of gas on product side

6a · 2 marks

  • M1

    single bond between O—O shown as a bond pair

  • M2

    each oxygen to have one O—H bonds shown and all lone pairs on oxygen

6b(i) · 2 marks

  • 1 mark

    (moles of hydrogen peroxide =) 0.17 / 34 OR 0.005

  • 1 mark

    3.01 × 1021

6b(ii) · 1 mark

  • 1 mark

    1.204 × 1022

6c · 2 marks

  • 1 mark

    it is a reducing agent

  • 1 mark

    it is an oxidising agent

6d · 1 mark

  • 1 mark

    BaO2

6e(i) · 2 marks

  • 1 mark

    particles move faster / particles have more kinetic energy

  • 1 mark

    more successful collisions / more collisions (involve particles) with equal or more than activation energy / more effective collisions

6e(ii) · 1 mark

  • 1 mark

    lowers the activation energy

7a · 2 marks

  • 1 mark

    dicarboxylic (acid)

  • 1 mark

    diol

7b(i) · 1 mark

  • 1 mark

    water

7b(ii) · 2 marks

  • 1 mark

    ester linkages between each ‘block’

  • 1 mark

    alternating ester linkages and at least two repeat units and continuation bonds

7b(iii) · 2 marks

  • 1 mark

    land-fills (may fill up)

  • 1 mark

    accumulation of plastics in oceans

  • 1 mark

    formation of toxic gases during burning

7c · 1 mark

  • 1 mark

    nylon / protein

8a · 1 mark

  • 1 mark

    has a double bond between carbon atoms / contains a C=C (bond)

8b · 2 marks

  • 1 mark

    orange

  • 1 mark

    to colourless

8c · 1 mark

  • 1 mark

    partially dissociates / does not completely ionise

8d · 1 mark

  • 1 mark

    carbon dioxide

8e · 2 marks

  • 1 mark

    react with or add an alcohol

  • 1 mark

    acid catalyst

8f(i) · 1 mark

  • 1 mark

    bacterial oxidation / reaction with (acidified) potassium manganate(VII)

8f(ii) · 1 mark

  • 1 mark

    sodium ethanoate and water

9a · 1 mark

  • 1 mark

    (chemically) combined with water

9b · 2 marks

  • 1 mark

    white precipitate

  • 1 mark

    soluble in excess resulting in colourless solution

9c · 1 mark

  • 1 mark

    white precipitate

9d · 4 marks

  • 1 mark

    anode dilute: oxygen (and water) / O2 (and H2O)

  • 1 mark

    anode concentrated: chlorine / Cl2

  • 1 mark

    cathode dilute: hydrogen / H2

  • 1 mark

    cathode concentrated: hydrogen / H2

9e · 1 mark

  • 1 mark

    ions can move in aqueous / ions cannot move in solid

10a(i) · 1 mark

  • 1 mark

    metal (compounds) can be toxic or poisonous or cause health problems

  • 1 mark

    (micro)plastics endanger aquatic life

  • 1 mark

    sewage contains (harmful) microbes / sewage causes health problems e.g. diseases or named diseases / animal waste causes health problems

  • 1 mark

    microbes or bacteria cause disease

  • 1 mark

    nitrates or phosphates or fertilisers cause eutrophication

10a(ii) · 1 mark

  • 1 mark

    (dissolved) oxygen for aquatic life / metal (compounds) that provide essential minerals for life

10b · 3 marks

  • M1

    sedimentation to remove (insoluble) solids / filtration to remove (insoluble) solids

  • M2

    carbonation or carbon to remove (bad) taste or odour

  • M3

    chlorination to kill microbes

10c · 1 mark

  • 1 mark

    (anhydrous) copper(II) sulfate goes from white to blue / (anhydrous) cobalt(II) chloride goes from blue to pink

10d · 1 mark

  • 1 mark

    (idea that) if boiling point is above 100 °C it is impure

Questions

  1. 1
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  2. 2
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  3. 3
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  4. 4
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  5. 5
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  6. 6
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  7. 7
    Question 78 marks
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  8. 8
    Question 89 marks
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  9. 9
    Question 99 marks
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  10. 10
    Question 107 marks
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