O Level Chemistry 5070 Paper 41, Oct/Nov 2025

Question paper and mark scheme40 marks4 questions

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Question paper

5070/41 · Oct/Nov 2025

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1

A student separates petroleum. Fig. 1.1 shows how the student assembles the apparatus.

Figure 1 of 2 for question 1
Figure 2 of 2 for question 1
a

State the name of the piece of apparatus labelled A in Fig. 1.1.

[1]
b

The student makes a mistake when assembling the apparatus. Describe this mistake.

[1]
c(i)

When it is correctly assembled, the apparatus shown in Fig. 1.1 is used to separate petroleum into useful substances. State the name of this separation process.

[1]
c(ii)

State the property of these substances that allows them to be separated.

[1]
d

State the name of the piece of apparatus the student uses to safely heat the petroleum in Fig. 1.1. Explain why this piece of apparatus is suitable. piece of apparatus .................................................................................................................... explanation ............................................................................................................................... ...................................................................................................................................................

[2]
2

A student investigates the temperature changes when an acid neutralises aqueous sodium hydroxide. The ionic equation for the reaction is shown. H++OH−→H2O The reaction is exothermic. The temperature change is used to determine the concentration of hydrogen ions in an acid. X is 1.60 mol/dm3 sodium hydroxide solution Y is an acid of concentration 2.00 mol/dm3 The student: step 1 fills the burette with Y step 2 stands a plastic cup inside a beaker step 3 uses a volumetric pipette to put 25.0 cm3 of X into the plastic cup step 4 measures the initial temperature of X and records it in Table 2.1 step 5 adds 5.0 cm3 of Y from the burette to the plastic cup step 6 stirs the mixture for 30 seconds and records in Table 2.1 the temperature of the mixture step 7 repeats steps 5 and 6 until a total of 40.0 cm3 of Y is added. Fig. 2.1 on page 6 shows two of the thermometer readings in °C during the experiment.

Figure 1 of 1 for question 2
a

Complete Table 2.1. You should: • record the student’s results for 5.0 cm3 and 30.0 cm3 using Fig. 2.1 • subtract the initial temperature of X from each temperature recorded to determine the temperature change. All temperatures and temperature changes should be recorded to +/−0.5 ∘C.

[4]
b

Plot a graph of the temperature change (y-axis) against the volume of Y (x-axis) on Fig. 2.2. Draw a line of best fit through the points where the temperature change is increasing. Draw a line of best fit through the points where the temperature change is decreasing. Extend both lines so that they cross.

[5]
c

Find the point on the graph where the two lines cross. Determine the volume of Y at this point. volume .................................................. cm3

[1]
d

X is 1.60 mol/dm3 sodium hydroxide solution. The formula of sodium hydroxide is NaOH. Calculate the number of moles of hydroxide ions, OH−, in 25.0 cm3 of X. number of moles .........................................................

[1]
e

The volume of Y in (c) is the volume needed to completely neutralise 25.0 cm3 of X. Use your answers to (c) and (d) to calculate the concentration of hydrogen ions, H+, in Y. H++OH−→H2O concentration .......................................... mol/dm3

[1]
f

Suggest why Y is added to X using a burette and not a measuring cylinder.

[1]
g

Suggest why the temperatures are recorded after 30 seconds and not immediately after mixing.

[1]
3

A student does a series of tests using aqueous solution Q and aqueous solution R.

a(i)

Solution Q is acidic. Solution Q contains one cation and one anion. The tests the student does on Q are shown in Table 3.1. Some of the observations for these tests are also shown. Describe the expected colour change in test 1.

[1]
a(ii)

A gas is produced in test 2. Predict one other observation made by the student in test 2.

[1]
a(iii)

Predict the identity of the gas produced in test 2.

[1]
a(iv)

Describe a test to confirm the identity of this gas. Include the result of a positive test. test .................................................................................................................................... result .................................................................................................................................

[2]
a(v)

Identify the cation and the anion in Q. cation ......................................................... anion .........................................................

[2]
b(i)

The tests the student does on R are shown in Table 3.2. Some of the observations for these tests are also shown. Describe how the student does a flame test.

[2]
b(ii)

Describe one additional observation expected in test 5 based on the observations in tests 4 and 5.

[1]
b(iii)

Describe one additional test to confirm the identity of the cation in R. Include the result of a positive test. test .................................................................................................................................... ........................................................................................................................................... result .................................................................................................................................

[3]
b(iv)

Identify the cation in R. cation ...........................................................................................................................

[1]
4

Alcohols are used as fuels to heat water. Plan an experiment to determine which alcohol, methanol or ethanol, releases more thermal energy per gram of alcohol burned. Your plan should describe the use of an alcohol burner, as shown in Fig. 4.1, to heat water. You should use water, methanol, ethanol and common laboratory apparatus. No other chemicals should be used. Your plan should include: • the additional apparatus needed • the method to use and the measurements to take • how the measurements are used to determine which alcohol releases more thermal energy per gram burned. You may draw a diagram to help answer the question.

[6]
Figure 1 of 1 for question 4

Mark scheme

5070/41 · Oct/Nov 2025

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1a · 1 mark

  • 1 mark

    (Liebig / water) condenser

1b · 1 mark

  • 1 mark

    bung inserted into conical flask

1c(i) · 1 mark

  • 1 mark

    fractional distillation

1c(ii) · 1 mark

  • 1 mark

    (different) boiling point (ranges)

1d · 2 marks

  • M1

    electric heater

  • M2

    petroleum is / fractions / separated substances are flammable

2a · 4 marks

  • M1

    temperature at 5 °C

  • M2

    temperature at 30 °C

  • M3

    all measurements and subtractions to .0 or .5 °C

  • M4

    all subtractions correct

2b · 5 marks

  • M1

    y-axis variable label and units

  • M2

    linear scale for y-axis ensures candidates points would take up more than half y-axis

  • M3

    8 or 9 points correctly plotted to ± ½ small square

  • M4

    two reasonable lines of best fit

  • M5

    intersection between lines of best fit

2c · 1 mark

  • 1 mark

    correct volume of Y from graph

2d · 1 mark

  • 1 mark

    0.04(00) mol

2e · 1 mark

  • 1 mark

    (d)  1000 / (c)

2f · 1 mark

  • 1 mark

    a burette is (more) accurate / precise / high resolution (than a measuring cylinder) ORA

2g · 1 mark

  • 1 mark

    to allow the temperature to stop changing / to reach maximum

3a(i) · 1 mark

  • 1 mark

    (from green to) yellow/orange/red

3a(ii) · 1 mark

  • 1 mark

    effervescence

3a(iii) · 1 mark

  • 1 mark

    hydrogen / H2

3a(iv) · 2 marks

  • M1

    lighted splint

  • M2

    pop sound

3a(v) · 2 marks

  • M1

    hydrogen / H+

  • M2

    chloride / Cl–

3b(i) · 2 marks

  • M1

    dip a wire / splint into R / put R into spray bottle

  • M2

    put/spray in blue / roaring / non-luminous / open air-hole (Bunsen) flame

3b(ii) · 1 mark

  • 1 mark

    dark(er) blue solution

3b(iii) · 3 marks

  • M1

    add sodium hydroxide (solution)

  • M2

    (light) blue precipitate

  • M3

    insoluble in excess (sodium hydroxide solution)

3b(iv) · 1 mark

  • 1 mark

    Copper(II) / Cu2+

4 · 6 marks

  • M1

    measuring cylinder / burette / volumetric pipette

  • M2

    thermometer

  • M3

    balance

  • M4

    suitable container for water to be heated in

  • M5

    heat a sample of water using an alcohol burner

  • M6

    use same volume/mass of water for both alcohols

  • M7

    measure the mass of the spirit burner with alcohol before and after burning

  • M8

    measure the temperature of water before and after burning

  • M9

    temperature change / mass change = temperature change per gram

  • M10

    greater temperature change per gram indicates more thermal energy per gram

Questions

  1. 1
    Question 16 marks
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  2. 2
    Question 214 marks
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  3. 3
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  4. 4
    Question 46 marks
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