O Level Chemistry 5070 Paper 22, May/June 2026

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5070/22 · May/June 2026

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1

Choose from the following compounds to answer the questions. Al2O3 CH3COOH C2H4 C3H8 CuO H2 K2O LiBr NH2OH NH3 SO2 Each compound can be used once, more than once or not at all. State which compound:

a

is an amphoteric oxide

[1]
b

has a molecule containing only two atoms

[1]
c

has a molecule with only 10 electrons

[1]
d

has an element with an oxidation number of +3

[1]
e

is an alkane.

[1]
2

Potassium superoxide, KO2, reacts with carbon dioxide to make potassium carbonate and oxygen. 4KO2(s)+2CO2(g)→2K2CO3(s)+3O2(g)

a

A sample of 13.0g of potassium superoxide reacts with excess carbon dioxide. Calculate the volume of oxygen, measured at r.t.p., that is formed. Give your answer to three significant figures. volume of oxygen = .................................................. dm3

[3]
b

Potassium superoxide is an ionic compound. Deduce the formula of a superoxide ion.

[1]
c

Potassium superoxide has a giant ionic lattice. Explain what is meant by the term giant ionic lattice.

[1]
d

Describe the separation, arrangement and motion of particles in solid carbon dioxide.

[3]
e

Draw a dot-and-cross diagram to show the electronic configuration in a molecule of carbon dioxide. Show only the outer shell electrons.

[2]
f

Explain why carbon dioxide has a low boiling point.

[1]
3

The equation for one of the reactions that happens in a catalytic converter is shown. 2NO(g)→O2(g)+N2(g) This decomposition reaction is exothermic.

Figure 1 of 1 for question 3
a

Complete the reaction pathway diagram in Figure 3.1 for this decomposition reaction. Label the: • axes • reactants and products • enthalpy change, ΔH.

[3]
b

The rate of the decomposition reaction is increased by using a catalyst. Explain how a catalyst increases the rate of the decomposition reaction.

[1]
c

Suggest why it is important that the solid catalyst in a catalytic converter has a large surface area.

[1]
d

The rate of the decomposition reaction increases when the pressure of the reactants is increased at constant temperature. Explain why.

[2]
e

The rate of the decomposition reaction increases when the temperature of the reactants is increased at constant pressure. Explain why.

[2]
4

Copper(II) sulfate is an ionic compound.

a

The electrolysis of aqueous copper(II) sulfate is done using copper or graphite electrodes. Complete Table 4.1 about the observations made in the two electrolysis reactions. Table 4.1

[4]
b

Molten barium iodide is electrolysed using graphite electrodes. Construct ionic half-equations to show the reactions at the anode and at the cathode. anode ........................................................................................................................ cathode .....................................................................................................................

[2]
c(i)

Graphite is a suitable material for the electrodes used in electrolysis because it is inert and has good electrical conductivity. State the meaning of the word inert.

[1]
c(ii)

Name one metal that is used as an inert electrode.

[1]
d(i)

The ionic equation for the reaction between magnesium and aqueous copper(II) sulfate is shown. Mg(s)+Cu2+(aq)→Mg2+(aq)+Cu(s) State the oxidation number of copper in copper(II) sulfate.

[1]
d(ii)

The reaction is an example of a redox reaction. Explain how the equation shows that both oxidation and reduction take place during the reaction. oxidation ............................................................................................................................ ........................................................................................................................................... reduction ........................................................................................................................... ...........................................................................................................................................

[2]
5

Zinc chloride is prepared by reacting excess zinc with warm dilute hydrochloric acid. Zn(s)+2HCl(aq)→ZnCl2(aq)+H2(g)

a

Use the equation to predict one observation made during this reaction.

[1]
b

Explain why an excess of zinc is used in this preparation.

[1]
c

A sample of 3.24g of zinc is added to 50.0cm3 of 1.50mol/dm3 hydrochloric acid. Show by calculation that the zinc is in excess.

[3]
d

State how excess zinc is removed from the reaction mixture.

[1]
e

Describe how pure dry zinc chloride crystals are prepared from aqueous zinc chloride.

[3]
f

The formula of a sample of zinc chloride crystals is ZnCl2⋅3H2O. Calculate the percentage by mass of water of crystallisation in these crystals. percentage by mass = .........................................................

[3]
g

Describe the effect of adding aqueous ammonia drop by drop until in excess to a sample of aqueous zinc chloride.

[2]
6

Copper and aluminium are metals. Both metals have good electrical conductivity.

a

Explain why both metals have good electrical conductivity. Use ideas about structure and bonding.

[1]
b(i)

Copper is a transition element but aluminium is not. Aluminium has a lower melting point and boiling point than copper. Suggest one other difference between the physical properties of these two metals.

[1]
b(ii)

Suggest one difference between the chemical properties of these two metals.

[1]
c(i)

Copper is used to make the alloy brass. Name the main element mixed with copper to make brass.

[1]
c(ii)

Brass is harder than pure copper. Explain why. Use ideas about structure and bonding.

[2]
d(i)

Aluminium is used to manufacture food containers because of its resistance to corrosion. Explain why aluminium is resistant to corrosion.

[2]
d(ii)

State one other use for aluminium and explain why aluminium is suitable for this use. use .................................................................................................................... explanation ........................................................................................................................ ...........................................................................................................................................

[2]
e(i)

Aluminium is manufactured by the electrolysis of purified bauxite mixed with cryolite. Carbon electrodes are used. Explain why cryolite is added to the purified bauxite.

[1]
e(ii)

Explain why the carbon anodes need to be regularly replaced.

[1]
7

Chloroethene is a monomer used to make poly(chloroethene). The displayed formula of chloroethene is shown.

a

Draw the structure of poly(chloroethene).

[2]
b

There is an accumulation of plastics such as poly(chloroethene) in the oceans. Suggest two properties of poly(chloroethene) that explain this accumulation. 1 ................................................................................................................................ 2 ................................................................................................................................

[2]
c(i)

Burning is used for the disposal of some plastics. This method of disposal causes environmental challenges. One of these challenges is the production of greenhouse gases. Name a greenhouse gas produced by burning plastics.

[1]
c(ii)

Another environmental challenge is the production of toxic gases. Name one toxic gas produced during the burning of plastics.

[1]
d

Phosgene, COCl2, decomposes when heated strongly. Show that the enthalpy change for the reaction is +101kJ/mol. Use the bond energies shown in Table 7.1. Table 7.1

[3]
8

This question is about carboxylic acids.

a

Vinegar is an aqueous solution containing ethanoic acid. During the production of vinegar, ethanoic acid is formed from ethanol. Water is also formed as a product. Describe the formation of ethanoic acid from ethanol during the production of vinegar. Include a symbol equation for the formation of ethanoic acid from ethanol and the conditions for the production of vinegar.

[2]
b

Draw the displayed formula of butanoic acid.

[1]
c

Ethyl ethanoate is a structural isomer of butanoic acid. State the meaning of the term structural isomer.

[1]
d(i)

Propanoic acid reacts with butan-1-ol to make an ester. Name the ester made in this reaction.

[1]
d(ii)

Draw the structural formula of the ester made in this reaction.

[1]
d(iii)

State one condition needed for this esterification reaction.

[1]
e

Deduce the molecular formula of an unbranched carboxylic acid that has only eight carbon atoms in its molecule and no other functional groups.

[2]

Mark scheme

5070/22 · May/June 2026

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1a · 1 mark

  • 1 mark

    Al2O3

1b · 1 mark

  • 1 mark

    H2

1c · 1 mark

  • 1 mark

    NH3

1d · 1 mark

  • 1 mark

    Al2O3

1e · 1 mark

  • 1 mark

    C3H8

2a · 3 marks

  • M1

    moles of KO2 = 13.0 / 71 OR 0.18310

  • M2

    mols of O2 = 0.75 × 13.0 / 71 OR 0.75 × 0.18310 OR 0.13732

  • M3

    vol of O2 = 3.30 (dm3)

2b · 1 mark

  • 1 mark

    O2−

2c · 1 mark

  • 1 mark

    regular arrangement of (alternating) positive and negative ions

2d · 3 marks

  • M1

    particles are touching each other

  • M2

    regular arrangement / ordered arrangement

  • M3

    vibrating (about a fixed point)

2e · 2 marks

  • M1

    two double bonds shown

  • M2

    lone pairs on oxygen correct

2f · 1 mark

  • 1 mark

    weak intermolecular forces

3a · 3 marks

  • 1 mark

    labels on axes

  • 1 mark

    reactants above products and reactants on the left

  • 1 mark

    downward arrow labelled as ΔH

3b · 1 mark

  • 1 mark

    activation energy is lowered

3c · 1 mark

  • 1 mark

    idea of maximising the amount of NO removed (from exhaust gases)

3d · 2 marks

  • M1

    particles are more crowded / distance between particles is smaller / more particles per unit volume

  • M2

    more collisions per second / greater collision frequency

3e · 2 marks

  • M1

    particles move faster / particles have more kinetic energy

  • M2

    more successful collisions / more collisions involve equal or more than activation energy / more particles with equal or more than activation energy / more effective collisions / more energetic collisions

4a · 4 marks

  • 1 mark

    copper electrodes anode observation: gets smaller / disappears / mass decreases

  • 1 mark

    copper electrodes cathode observation: gets bigger / (coated with) pink (solid) / mass increases

  • 1 mark

    graphite electrodes anode observation: bubbles / fizzes

  • 1 mark

    graphite electrodes cathode observation: (coated with) pink (solid) / gets bigger / mass increases

4b · 2 marks

  • 1 mark

    (anode) 2I− → I2 + 2e−

  • 1 mark

    (cathode) Ba2+ + 2e− → Ba

4c(i) · 1 mark

  • 1 mark

    does not react with electrolyte or products

4c(ii) · 1 mark

  • 1 mark

    platinum

4d(i) · 1 mark

  • 1 mark

    +2

4d(ii) · 2 marks

  • 1 mark

    (oxidation) magnesium (atom) loses electrons / oxidation number of magnesium increases

  • 1 mark

    (reduction) copper(II) ions gain electrons / oxidation number of copper decreases

5a · 1 mark

  • 1 mark

    bubbles / fizzes / effervesces / colourless solution obtained

5b · 1 mark

  • 1 mark

    to use up all the acid

5c · 3 marks

  • 1 mark

    mol of zinc = 0.04985 OR 3.24 / 65 (or mol of HCl = 0.050 × 1.50 OR 0.075)

  • 1 mark

    so mols of HCl needed = 0.04985 × 2 OR 0.0997 (or so mol of zinc needed = 0.075 ÷ 2 OR 0.0375)

  • 1 mark

    actual mol of HCl = 0.050 × 1.50 OR 0.075 (so not enough HCl) (or actual mol of zinc = 0.04985 (so excess zinc) / so actual mass of zinc is 2.4375)

5d · 1 mark

  • 1 mark

    filtration

5e · 3 marks

  • M1

    heat solution to get a saturated solution / heat to reduce volume by half / heat to reach crystallisation point / heat to the first appearance of crystals

  • M2

    allow (solution) to evaporate slowly / leave (solution) to cool

  • M3

    filter off crystals, wash with water and dry with filter paper

5f · 3 marks

  • M1

    Mr of ZnCl2 = 136 OR formula mass of 3H2O = 54

  • M2

    Mr of hydrated salt = 190 OR (%) = 100 × 54/190

  • M3

    = 28 / 28.4

5g · 2 marks

  • 1 mark

    white precipitate

  • 1 mark

    soluble in excess resulting in colourless solution

6a · 1 mark

  • 1 mark

    have mobile electrons

6b(i) · 1 mark

  • 1 mark

    aluminium has a lower density

6b(ii) · 1 mark

  • 1 mark

    copper has coloured compounds / copper has more than one oxidation state

6c(i) · 1 mark

  • 1 mark

    zinc

6c(ii) · 2 marks

  • M1

    brass has particles with different sizes

  • M2

    layers (of atoms or ions) in brass cannot slide (as easily as in pure copper)

6d(i) · 2 marks

  • 1 mark

    has an oxide layer (on surface)

  • 1 mark

    outer layer is waterproof / does not let water through / is impermeable (to water and/or oxygen)

6d(ii) · 2 marks

  • 1 mark

    aircraft / overhead (electrical) cables / window frames

  • 1 mark

    property linked to use: low density / good electrical conductivity / malleable / does not corrode

6e(i) · 1 mark

  • 1 mark

    lowers the operating temperature (of the cell) / increases the electrical conductivity of the electrolyte

6e(ii) · 1 mark

  • 1 mark

    carbon reacts with oxygen formed to produce carbon dioxide

7a · 2 marks

  • M1

    correct repeat unit

  • M2

    continuation bonds (and n shown)

7b · 2 marks

  • 1 mark

    insoluble in water

  • 1 mark

    non-biodegradable / does not decompose / does not decay

  • 1 mark

    unreactive (with water or air)

7c(i) · 1 mark

  • 1 mark

    carbon dioxide / water

7c(ii) · 1 mark

  • 1 mark

    carbon monoxide

7d · 3 marks

  • M1

    energy associated with bonds broken = 740 + 2 × 340 OR 1420

  • M2

    energy associated with making bonds = 242 + 1077 OR 1319

  • M3

    enthalpy change = 1420 – 1319

8a · 2 marks

  • 1 mark

    CH3CH2OH + O2 → CH3COOH + H2O

  • 1 mark

    bacteria / oxygen

8b · 1 mark

  • 1 mark

    displayed formula of butanoic acid with O-H bond displayed

8c · 1 mark

  • 1 mark

    same molecular formula but different structural formulas

8d(i) · 1 mark

  • 1 mark

    butyl propanoate

8d(ii) · 1 mark

  • 1 mark

    CH3CH2COOCH2CH2CH2CH3

8d(iii) · 1 mark

  • 1 mark

    heat / reflux / acid catalyst

8e · 2 marks

  • 2 marks

    C8H16O2

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