O Level Chemistry 5070 Paper 21, May/June 2026

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5070/21 · May/June 2026

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1

Choose from the following compounds to answer the questions. AlCl3 CH4 C2H4 CO2 KBr NH2OH NO Na2O SO2 ZnO Each compound can be used once, more than once or not at all. State which compound:

a

is amphoteric

[1]
b

has a molecule with only three atoms

[1]
c

has a molecule with only 18 electrons

[1]
d

has an element with an oxidation number of +2

[1]
e

is unsaturated.

[1]
2

Sodium azide, NaN3, decomposes when heated to make sodium and nitrogen. 2NaN3(s)→2Na(s)+3N2(g)

a

A sample of 13.6g of sodium azide is fully decomposed. Calculate the volume of nitrogen, measured at r.t.p., that is formed. Give your answer to three significant figures. volume of nitrogen = .................................................. dm3

[3]
b(i)

Sodium azide has a giant ionic lattice. Explain what is meant by the term giant ionic lattice.

[1]
b(ii)

Predict two physical properties of sodium azide. 1 ........................................................................................................................................ 2 ........................................................................................................................................

[2]
b(iii)

Deduce the formula of an azide ion.

[1]
c

Describe the separation, arrangement and motion of the molecules in nitrogen gas.

[3]
d

Draw a dot-and-cross diagram to show the electronic configuration in a molecule of nitrogen. Show only the outer shell electrons.

[1]
e

Explain why nitrogen has a very low boiling point.

[1]
3

Hydrogen reacts with oxygen to make water. 2H2(g)+O2(g)→2H2O(g) Figure 3.1 shows the reaction pathway diagram for this reaction.

Figure 1 of 3 for question 3
Figure 2 of 3 for question 3
Figure 3 of 3 for question 3
a(i)

The reaction is exothermic. Explain how the reaction pathway diagram shows that the reaction is exothermic.

[1]
a(ii)

Explain why the reaction is exothermic. Use ideas about bond breaking and bond making.

[2]
b

Explain what is meant by the term activation energy, Ea, used in Figure 3.1.

[1]
c

The equation for the overall chemical reaction that takes place within a hydrogen–oxygen fuel cell is shown. 2H2(g)+O2(g)→2H2O(l) Describe one advantage and one disadvantage of using a hydrogen–oxygen fuel cell to power a motor vehicle rather than using a gasoline engine. advantage ................................................................................................................................. ................................................................................................................................................... disadvantage ............................................................................................................................ ...................................................................................................................................................

[2]
d

The rate of reaction between hydrogen gas and oxygen gas decreases when the pressure is decreased at constant temperature. Explain why.

[2]
e

The rate of reaction between hydrogen gas and oxygen gas decreases when the temperature is decreased at constant pressure. Explain why.

[2]
4

Potassium iodide is an ionic compound.

a

Concentrated and dilute aqueous potassium iodide are separately electrolysed using graphite electrodes. Complete Table 4.1 about the products of the two electrolysis reactions. Table 4.1

[4]
b

Molten potassium iodide is electrolysed using graphite electrodes. Construct ionic half-equations to show the reactions at the anode and at the cathode. anode ........................................................................................................................................ cathode .....................................................................................................................................

[2]
c

State two reasons why graphite is a suitable material for the electrodes used in electrolysis. 1 ................................................................................................................................................ 2 ................................................................................................................................................

[2]
d(i)

The ionic equation for the reaction between aqueous potassium iodide and aqueous copper(II) chloride is shown. 4I−+2Cu2+→2CuI+I2 State the oxidation number of copper in copper(II) chloride.

[1]
d(ii)

The reaction is an example of a redox reaction. Explain how the equation shows that both oxidation and reduction take place during the reaction. oxidation ............................................................................................................................ ........................................................................................................................................... reduction ........................................................................................................................... ...........................................................................................................................................

[2]
5

Aluminium sulfate is prepared by reacting excess aluminium with hot dilute sulfuric acid. 2Al(s)+3H2SO4(aq)→Al2(SO4)3(aq)+3H2(g)

a

Use the equation to predict one observation made during this reaction.

[1]
b

Explain why an excess of aluminium is used in this preparation.

[1]
c

A sample of 3.24g of aluminium is added to 50.0cm3 of 2.50mol/dm3 sulfuric acid. Show by calculation that the aluminium is in excess.

[3]
d

Describe how excess aluminium is removed from the reaction mixture.

[1]
e

Describe how pure dry aluminium sulfate crystals are prepared from aqueous aluminium sulfate.

[3]
f

The formula of aluminium sulfate crystals is Al2(SO4)3⋅16H2O. Calculate the percentage by mass of water of crystallisation in these crystals. percentage by mass = ..............................

[3]
g

Describe the effect of adding aqueous sodium hydroxide drop by drop until in excess to a sample of aqueous aluminium sulfate.

[2]
6

Iron is a transition element. Iron has good electrical conductivity.

a

State two chemical properties that are typical of a transition element. 1 ................................................................................................................................................ 2 ................................................................................................................................................

[2]
b

Explain why iron has good electrical conductivity. Use ideas about structure and bonding.

[1]
c(i)

Iron is used to make stainless steel. Name two elements that are mixed with iron to make stainless steel. 1 ........................................................................................................................................ 2 ........................................................................................................................................

[2]
c(ii)

Stainless steel is used to make cutlery because it is hard. Explain why stainless steel is harder than pure iron. Use ideas about structure and bonding.

[2]
c(iii)

Describe the extraction of iron from hematite in the blast furnace. You may include word equations in your answer.

[5]
7

Proteins are natural condensation polymers. Figure 7.1 shows a section of a protein.

Figure 1 of 2 for question 7
Figure 2 of 2 for question 7
a

Define the term condensation in the phrase condensation polymerisation.

[1]
b(i)

Name the type of monomer used to make proteins.

[1]
b(ii)

Draw the general structure of the monomer used to make proteins.

[1]
b(iii)

Proteins contain the amide linkage. Circle an amide linkage on Figure 7.1.

[1]
c(i)

Nylon is a synthetic polyamide. Name the two types of monomer that are used to make nylon. ............................................................... and ..............................................................

[2]
c(ii)

Describe one environmental challenge caused by the disposal of plastics such as nylon.

[1]
8

This question is about alcohols.

a

Describe the manufacture of ethanol from ethene. Include a symbol equation and the conditions for the manufacture.

[3]
b

Draw the displayed formula of butan-2-ol.

[1]
c(i)

Ethanol reacts with propanoic acid to form an ester. State the name of this ester.

[1]
c(ii)

Draw the structural formula of this ester.

[1]
c(iii)

State one condition needed for this esterification reaction.

[1]
d

Deduce the molecular formula of an unbranched alcohol that has only eight carbon atoms in its molecule and only one alcohol functional group.

[2]

Mark scheme

5070/21 · May/June 2026

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1a · 1 mark

  • 1 mark

    ZnO

1b · 1 mark

  • 1 mark

    CO2 / SO2

1c · 1 mark

  • 1 mark

    NH2OH

1d · 1 mark

  • 1 mark

    ZnO / NO

1e · 1 mark

  • 1 mark

    C2H4

2a · 3 marks

  • 1 mark

    moles of NaN3 = 13.6 / 65 OR 0.20923

  • 1 mark

    mols of N2 = 1.5 × 13.6 / 65 OR 1.5  0.20923 OR 0.313846

  • 1 mark

    vol of N2 = 7.53 (dm3)

2b(i) · 1 mark

  • 1 mark

    regular arrangement of (alternating) positive and negative ions

2b(ii) · 2 marks

  • 1 mark

    high melting point / high boiling point

  • 1 mark

    conducts electricity in (aqueous) solution

2b(iii) · 1 mark

  • 1 mark

    N3–

2c · 3 marks

  • 1 mark

    (separation) particles are widely apart / large distance between particles / spread far apart / are far apart

  • 1 mark

    (arrangement) random arrangement / irregular arrangement

  • 1 mark

    (motion) moving (very) fast / have a large amount of kinetic energy / random (motion)

2d · 1 mark

  • 1 mark

    Triple bond shared between two N atoms and one non-bonded pair on each N atom

2e · 1 mark

  • 1 mark

    weak intermolecular forces

3a(i) · 1 mark

  • 1 mark

    energy of products less than energy of reactants

3a(ii) · 2 marks

  • 1 mark

    bond breaking endothermic AND bond making exothermic / energy absorbed to break bonds AND energy released on making bonds

  • 1 mark

    more energy released than absorbed

3b · 1 mark

  • 1 mark

    minimum energy that colliding particles must have in order to react

3c · 2 marks

  • 1 mark

    advantage: water is the only product / no carbon dioxide made / higher efficiency / quieter / transfer more energy per gram of fuel / (hydrogen is) a renewable (source of energy)

  • 1 mark

    disadvantage: idea of difficult to store the hydrogen (under pressure) / limited availability of hydrogen

3d · 2 marks

  • 1 mark

    particles are less crowded / distance between particles is greater / fewer particles per unit volume

  • 1 mark

    fewer collisions per second / lower collision frequency

3e · 2 marks

  • 1 mark

    particles move slower / particles have less kinetic energy

  • 1 mark

    less successful collisions / fewer collisions with equal or more than activation energy / fewer particles with equal or more than activation energy / less effective collisions / less energetic collisions

4a · 4 marks

  • 1 mark

    concentrated aqueous potassium iodide, product formed at anode: iodine / I2

  • 1 mark

    dilute aqueous potassium iodide, product formed at anode: oxygen (and water) / O2 (and H2O)

  • 1 mark

    concentrated aqueous potassium iodide, product formed at cathode: hydrogen / H2

  • 1 mark

    dilute aqueous potassium iodide, product formed at cathode: hydrogen / H2

4b · 2 marks

  • 1 mark

    (anode) 2I– → I2 + 2e–

  • 1 mark

    (cathode) K+ + e– → K

4c · 2 marks

  • 1 mark

    inert / does not react with electrolyte or products

  • 1 mark

    good electrical conductivity

4d(i) · 1 mark

  • 1 mark

    +2

4d(ii) · 2 marks

  • 1 mark

    (oxidation) iodide(ion) loses electrons / oxidation number of iodine increases

  • 1 mark

    (reduction) copper(II) ions gain electrons / oxidation number of copper decreases

5a · 1 mark

  • 1 mark

    bubbles / fizzes / effervesces / colourless solution obtained

5b · 1 mark

  • 1 mark

    to use up all the acid

5c · 3 marks

  • 1 mark

    mol of aluminium = 0.12 OR 3.24 / 27 (OR mol of H2SO4 = 0.050  2.50 OR 0.125)

  • 1 mark

    so mols of H2SO4 needed = 0.12  1.5 OR 0.18 (OR so mol of aluminium needed 0.0125 ÷ 1.5 OR 0.0833)

  • 1 mark

    actual mol of H2SO4 = 0.050  2.50 OR 0.125 (so not enough H2SO4) (OR actual mol of aluminium = 0.12 (so excess aluminium) OR mass aluminium needed is 2.25 g (so is in excess))

5d · 1 mark

  • 1 mark

    filtration

5e · 3 marks

  • M1

    heat solution to get a saturated solution / heat to reduce volume by half / heat to reach crystallisation point / heat to the first appearance of crystals

  • M2

    allow (solution) to evaporate slowly / leave (solution) to cool

  • M3

    filter off crystals, wash with water and dry with filter paper

5f · 3 marks

  • 1 mark

    Mr of Al2(SO4)3 = 342 or formula mass of 16H2O = 288

  • 1 mark

    Mr of hydrated salt = 630 OR (%)100  288/630

  • 1 mark

    = 46 / 45.7

5g · 2 marks

  • 1 mark

    white precipitate

  • 1 mark

    soluble in excess resulting in colourless solution

6a · 2 marks

  • 1 mark

    act as catalysts

  • 1 mark

    more than one oxidation state (in compounds)

  • 1 mark

    form coloured compounds

6b · 1 mark

  • 1 mark

    has mobile electrons

6c(i) · 2 marks

  • 1 mark

    carbon

  • 1 mark

    nickel

  • 1 mark

    chromium

6c(ii) · 2 marks

  • 1 mark

    stainless steel has particles with different sizes

  • 1 mark

    layers (of atoms or ions) in steel cannot slide as easily as in pure iron

6c(iii) · 5 marks

  • 1 mark

    coke burns/reacts with oxygen/air to make carbon dioxide / carbon + oxygen → carbon dioxide / C + O2 → CO2

  • 1 mark

    coke reacts with carbon dioxide to make carbon monoxide / carbon + carbon dioxide → carbon monoxide / C + CO2 → 2CO

  • 1 mark

    carbon monoxide reacts with iron(III) oxide to make iron / carbon monoxide + iron(III) oxide → carbon dioxide + iron / Fe2O3 + 3CO → 3CO2 + 2Fe

  • 1 mark

    calcium carbonate forms (carbon dioxide and) calcium oxide / calcium carbonate → carbon dioxide + calcium oxide / CaCO3 → CaO + CO2

  • 1 mark

    calcium oxide reacts with sand to make slag / calcium oxide + silicon dioxide → calcium silicate / CaO + SiO2→ CaSiO3

7a · 1 mark

  • 1 mark

    forms compound and a small molecule / where two molecules react with loss of a small molecule

7b(i) · 1 mark

  • 1 mark

    amino acid

7b(ii) · 1 mark

  • 1 mark

    Correct displayed or structural formula of the amino acid monomer

7b(iii) · 1 mark

  • 1 mark

    any one circle around an amide / peptide group

7c(i) · 2 marks

  • 1 mark

    diamine

  • 1 mark

    dicarboxylic acid

7c(ii) · 1 mark

  • 1 mark

    land-fills (may fill up) / accumulation of plastics/nylon in oceans / formation of toxic gases during burning

8a · 3 marks

  • 1 mark

    C2H4 + H2O → CH3CH2OH

  • 1 mark

    300 °C

  • 1 mark

    60 atm / 6000 kPa

  • 1 mark

    acid catalyst

8b · 1 mark

  • 1 mark

    Displayed formula of butan-2-ol

8c(i) · 1 mark

  • 1 mark

    ethyl propanoate

8c(ii) · 1 mark

  • 1 mark

    CH3CH2COOCH2CH3

8c(iii) · 1 mark

  • 1 mark

    heat / reflux / acid catalyst

8d · 2 marks

  • 2 marks

    C8H18O

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