IGCSE Chemistry 0620 Paper 22, Oct/Nov 2025

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0620/22 · Oct/Nov 2025

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1

What happens to the volume of a fixed mass of gas when the temperature is increased or the pressure is decreased?

increased temperaturedecreased pressure
Avolume decreasedvolume decreased
Bvolume decreasedvolume increased
Cvolume increasedvolume decreased
Dvolume increasedvolume increased
2

The diagram shows the heating curve for a substance. Between which two points do the particles of the substance change from being in fixed positions to being mobile? A P and Q B Q and R C S and T D T and U

Figure 1 of 1 for question 2
3

A student investigates the diffusion of ammonia gas, NH3, and hydrogen chloride gas, HCl. Two sets of apparatus are set up as shown at room temperature and pressure. The damp red litmus paper in apparatus 1 changes colour after 30 seconds. How long does it take for the damp blue litmus paper in apparatus 2 to change colour? A 21 seconds B 30 seconds C 64 seconds D The damp blue litmus paper does not change colour.

Figure 1 of 2 for question 3
Figure 2 of 2 for question 3
4

Which row describes elements, compounds and mixtures?

elementscompoundsmixtures
Aall the atoms are the same typecontain different atoms chemically joined togethercan be separated using physical processes
Ball the atoms are the same typecan be separated into new substances using chemical processescontain different atoms chemically joined together
Ccan be separated into new substances using chemical processesall the atoms are the same typecontain different atoms chemically joined together
Dcontain different atoms chemically joined togetherall the atoms are the same typecan be separated using physical processes
5

Which statement about atoms or ions is correct? A The mass number of an atom is the total number of nucleons and protons. B The electronic configuration of an aluminium ion, Al3+, is 2,8,3. C Hydrogen is the only atom that has an incomplete first electron shell. D Most of the volume of an atom is taken up by its nucleus.

6

Which two values are used to calculate the relative atomic mass of a sample of boron?

value 1value 2
Athe total number of boron isotopesthe total number of boron atoms
Bthe relative abundance of each boron isotope in the samplethe relative mass of each boron isotope
Cthe relative abundance of each boron isotope in the samplethe total number of boron atoms
Dthe total number of boron isotopesthe relative mass of each boron isotope
7

Which statement describes the structure of sodium chloride? A a lattice of alternating positive and negative ions B a lattice of positive ions surrounded by a 'sea' of delocalised electrons C a mixture of sodium and chlorine atoms D a regular lattice of sodium and chlorine atoms

8

Graphite and diamond are both forms of the element carbon. Which row shows the number of other carbon atoms that each carbon atom is covalently bonded to in graphite and in diamond?

graphitediamond
A33
B34
C43
D44
Figure 1 of 1 for question 8
9

Which row describes the structure and bonding in cobalt?

structurebonding
Agiantionic
Bsimpleionic
Cgiantmetallic
Dsimplemetallic
Figure 1 of 1 for question 9
10

The equation for the combustion of ethanol is shown. C2H5OH+3O2→2CO2+3H2O The relative molecular mass, Mr, of ethanol is 46. Which statement about the reaction is correct? A 4.6 g of ethanol produces 4.4 g of carbon dioxide. B 92 g of ethanol produces 88 g of carbon dioxide and 108 g of water. C 138 g of ethanol reacts with 32 g of oxygen. D 184 g of ethanol produces 216 g of water.

11

A compound contains 40.0% carbon, 6.7% hydrogen and 53.3% oxygen only. The relative molecular mass, Mr, of the compound is 60. Which row shows the empirical formula and the molecular formula of the compound?

empirical formulamolecular formula
ACH2OCH2O
BCH2OC2H4O2
CC3H7O3C3H7O3
DC3H8OC3H8O
12

Hydrogen–oxygen fuel cells are used in electric cars. Three statements about these fuel cells are listed. 1 The process in the cell is called electrolysis. 2 Water is broken down in the cell to produce hydrogen, oxygen and electricity. 3 Water is the only chemical product formed in the reaction. Which statements are correct? A 1 and 2 B 1 and 3 C 2 only D 3 only

13

A solution of copper(II) sulfate can be electrolysed using copper electrodes or carbon electrodes. Which statements are correct? 1 Using copper electrodes, oxygen gas forms at the anode. 2 Using copper electrodes, copper atoms lose electrons at the anode. 3 Using carbon electrodes, copper metal forms at the cathode. 4 Using carbon electrodes, copper ions gain electrons at the cathode. A 1 and 2 B 1 and 3 C 2, 3 and 4 D 4 only

14

The equation for the combustion of hydrazine, N2H4, is shown.

bondbond energy in kJ / mol
N–H391
N=N409
N≡N944
O–H463
O=O496

What is the overall enthalpy change for the combustion of one mole of hydrazine? A –327 kJ / mol B –111 kJ / mol C +111 kJ / mol D +327 kJ / mol

Figure 1 of 1 for question 14
15

Dissolving ammonium chloride in water is an endothermic change. Which row shows the energy change and temperature change of the mixture during the dissolving of ammonium chloride?

energy changetemperature change
Aenergy is absorbeddecrease
Benergy is absorbedincrease
Cenergy is releaseddecrease
Denergy is releasedincrease
16

Aqueous sodium thiosulfate, Na2S2O3, reacts with dilute hydrochloric acid to form a yellow precipitate of sulfur. Na2S2O3(aq)+2HCl(aq)→2NaCl(aq)+H2O(l)+S(s)+SO2(g) The precipitate forms more quickly when the reactants are heated. Which statements explain this observation? 1 The reacting particles collide more frequently. 2 The collisions between reacting particles have more energy. 3 The activation energy of the reaction is lower. A 1 and 2 B 1 and 3 C 1 only D 2 and 3

17

Which statement about the conditions used in the Haber process and in the Contact process is correct? A The typical pressure used in the Haber process is similar to that used in the Contact process. B The typical temperature used in the Haber process is similar to that used in the Contact process. C The Haber process uses a vanadium(V) oxide catalyst, and the Contact process uses an iron catalyst. D Both processes produce an acidic gas.

18

The equation shows the equilibrium between dinitrogen tetroxide, N2O4, and nitrogen dioxide, NO2. The colours of the reactant and product are shown. N2O4(g)colourless⇌2NO2(g)brown The forward reaction is endothermic. Which statement is not correct? A At equilibrium, the concentrations of the reactant and the product stay constant. B At equilibrium, the rate of the forward reaction is equal to the rate of the reverse reaction. C When the pressure is increased, a darker brown colour is seen. D When the temperature is increased, a darker brown colour is seen.

19

What is the oxidation number of chromium in the Cr2O72− ion? A –2 B –1 C +6 D +12

20

Which method is used to prepare a pure, dry sample of lead(II) chloride? A mix aqueous lead(II) nitrate and dilute hydrochloric acid → filter → crystallise and dry the filtrate B mix aqueous lead(II) nitrate and dilute hydrochloric acid → filter → wash and dry the residue C mix solid lead(II) hydroxide and aqueous sodium chloride → filter → crystallise and dry the filtrate D mix solid lead(II) hydroxide and aqueous sodium chloride → filter → wash and dry the residue

21

Phosphorus is an element in Group V of the Periodic Table. It burns in air to form an oxide that dissolves in water to form a solution with a pH of 1. Which row describes this oxide of phosphorus?

metal oxidenon-metal oxideacidic oxidebasic oxide
A✓X✓Xkey
B✓XX✓✓= yes
CX✓✓XX= no
DX✓X✓
Figure 1 of 1 for question 21
22

The equation shows the reaction between aqueous hydrogen bromide and aqueous ammonia. HBr(aq)+NH3(aq)→NH4+(aq)+Br−(aq) Which statement describes the role of aqueous hydrogen bromide? A It is a catalyst. B It is a reducing agent. C It is a proton acceptor. D It is a proton donor.

23

Which statement about the elements in Group I is correct? A Hydrogen is produced when Group I elements react with water. B Ions of Group I elements have a 1– charge. C Sodium is more reactive than potassium. D Solid sodium is a poor electrical conductor.

24

Which row describes the colour and state of iodine at room temperature and pressure?

colourstate
Agreenliquid
Bgrey-blacksolid
Cpurplesolid
Dred-brownliquid
25

Part of the Periodic Table is shown. Which element is an inert gas?

Figure 1 of 1 for question 25
26

Four different metals are separately added to water. The oxide of each metal is separately heated with carbon. The results are shown.

metalmetal with watermetal oxide with carbon
Qno reactionbrown solid forms
Rrapid fizzingno reaction
Sa few bubblesno reaction
Ta few bubblesgrey solid forms

What is the order of reactivity of the four metals, least reactive first? A Q → T → S → R B Q → S → T → R C R → S → T → Q D R → T → S → Q

Figure 1 of 1 for question 26
27

An iron nail is fully covered with zinc to prevent it from rusting. Which row describes this method of protection and explains why zinc is used to protect the iron nail?

method of protectionreason zinc is used
Abarrier method and sacrificial protectionzinc is more reactive than iron
Bbarrier method and sacrificial protectioniron is more reactive than zinc
Csacrificial protection onlyzinc is more reactive than iron
Dbarrier method onlyiron is more reactive than zinc
28

Iron is extracted from hematite in the blast furnace. Which reaction increases the temperature in the blast furnace to over 1500 °C? A calcium carbonate → calcium oxide + carbon dioxide B calcium oxide + silicon(IV) oxide → calcium silicate C carbon + oxygen → carbon dioxide D carbon dioxide + carbon → carbon monoxide

29

Aluminium is extracted by the electrolysis of purified bauxite. Which row shows the half-equations at the electrodes and explains why one of the electrodes has to be replaced regularly?

half-equation at anodehalf-equation at cathodeelectrode replacement
A2O2−→O2+4e−Al3++3e−→Alcathode replaced as it gets coated with aluminium
B2O2−→O2+4e−Al3++3e−→Alanode replaced as it burns away in oxygen
CAl3++3e−→Al2O2−→O2+4e−cathode replaced as it burns away in oxygen
DAl3++3e−→Al2O2−→O2+4e−anode replaced as it gets coated with aluminium
30

Which flow chart describes the correct treatment sequence of the domestic water supply? A filtration → chlorination → sedimentation B sedimentation → chlorination → filtration C chlorination → filtration → sedimentation D sedimentation → filtration → chlorination

31

Which statement about oxides of nitrogen is correct? A They are made in car engines by the incomplete combustion of gasoline at a high temperature. B They are made in car engines when nitrogen in gasoline reacts with oxygen in air at a high temperature. C They are removed from car exhausts by catalytic converters and form nitrogen and sulfur dioxide. D They are removed from car exhausts when they react with carbon monoxide in catalytic converters.

32

The alkenes are a homologous series. Which statement about the members of the homologous series of the alkenes is correct? A They have the same functional group. B They have the same relative molecular mass. C They have different chemical properties. D They have different general formulae.

33

The diagram represents two processes, X and Y, and their effect, Z, in increasing global warming. Which row identifies X, Y and Z?

XYZ
Aabsorption of thermal energy by greenhouse gasesemission of thermal energy to the Earthreduced thermal energy loss to space
Bemission of thermal energy by greenhouse gasesemission of thermal energy to spacereduced thermal energy loss to space
Cabsorption of thermal energy by greenhouse gasesemission of thermal energy to the Earthincreased thermal energy loss to space
Demission of thermal energy by greenhouse gasesemission of thermal energy to spaceincreased thermal energy loss to space
Figure 1 of 2 for question 33
Figure 2 of 2 for question 33
34

Which structures are structural isomers of each other? A 1, 2, 3 and 4 B 1, 2 and 4 only C 1 and 3 only D 2 and 4 only

Figure 1 of 4 for question 34
Figure 2 of 4 for question 34
Figure 3 of 4 for question 34
Figure 4 of 4 for question 34
35

The structure of an ester is shown. What is the name of this ester? A ethyl methanoate B methyl ethanoate C propyl methanoate D methyl propanoate

36

Which row shows the products obtained by the cracking of a large alkane?

alkenehydrogenwater
A✓✓✓key
B✓✓X✓= yes
C✓X✓X= no
DX✓✓
37

Ethanol is produced by the fermentation of aqueous glucose or by the catalytic addition of steam to ethene. Which row shows some advantages and disadvantages of these processes?

fermentation of aqueous glucosecatalytic addition of steam to ethene
advantagedisadvantageadvantagedisadvantage
Afast reactionethanol produced continuouslyalmost pure ethanol formedrenewable raw material
Bethanol produced in batchesslow reactionfast reactionethanol produced continuously
Crenewable raw materialethanol produced in batchesalmost pure ethanol formedslow reaction
Drenewable raw materialdilute aqueous ethanol formedfast reactionnon-renewable raw material
38

Propenoic acid is an organic compound that is both an alkene and a carboxylic acid. The structure of propenoic acid is shown. Which structure represents one repeat unit of the addition polymer formed from propenoic acid?

Figure 1 of 1 for question 38
39

Which item of apparatus is used to measure 13.7 cm3 of dilute hydrochloric acid? A a balance B a burette C a conical flask D a volumetric pipette

40

Chromatography is used to separate and analyse mixtures of soluble substances. The first steps of the process are listed. ● apply sample to baseline ● develop chromatogram in solvent What is the next step in the process to detect soluble colourless substances? A calculate the Rf values B compare the results with known substances C count the number of spots D use a suitable locating agent

Mark scheme

0620/22 · Oct/Nov 2025

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Question 1

Answer: D

Question 2

Answer: B

Question 3

Answer: C

Question 4

Answer: A

Question 5

Answer: C

Question 6

Answer: B

Question 7

Answer: A

Question 8

Answer: B

Question 9

Answer: C

Question 10

Answer: D

Question 11

Answer: B

Question 12

Answer: D

Question 13

Answer: C

Question 14

Answer: A

Question 15

Answer: A

Question 16

Answer: A

Question 17

Answer: B

Question 18

Answer: C

Question 19

Answer: C

Question 20

Answer: B

Question 21

Answer: C

Question 22

Answer: D

Question 23

Answer: A

Question 24

Answer: B

Question 25

Answer: C

Question 26

Answer: A

Question 27

Answer: A

Question 28

Answer: C

Question 29

Answer: B

Question 30

Answer: D

Question 31

Answer: D

Question 32

Answer: A

Question 33

Answer: A

Question 34

Answer: C

Question 35

Answer: D

Question 36

Answer: B

Question 37

Answer: D

Question 38

Answer: B

Question 39

Answer: B

Question 40

Answer: D

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