IGCSE Chemistry 0620 Paper 32, May/June 2025

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0620/32 · May/June 2025

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1

A list of substances is shown. aluminium bromine calcium carbon dioxide iron magnesium magnesium oxide neon oxygen potassium sulfur dioxide Answer the following questions about these substances. Each substance may be used once, more than once or not at all. State which substance is:

a

an element which forms an ion with a 2– charge

[1]
b

an ionic compound

[1]
c

used as a catalyst

[1]
d

approximately 21% of clean, dry air

[1]
e

a gas needed for photosynthesis

[1]
f

the most reactive metal in the list

[1]
g

a gas that is tested for using acidified aqueous potassium manganate(VII)

[1]
h

a noble gas

[1]
i

in Group VII.

[1]
2

This question is about sea water and the substances found in sea water.

Figure 1 of 1 for question 2
a(i)

Table 2.1 shows the masses of some of the compounds formed when 500 cm3 of sea water is evaporated. Table 2.1

compoundformulamass of compound/g
sodium chlorideNaCl7.0
MgSO42.5
potassium bromideKBr1.5
calcium carbonateCaCO31.0

Answer these questions using the information from Table 2.1. State the chemical name of MgSO4.

[1]
a(ii)

The total mass of compounds formed from 500 cm3 of sea water is 12.0 g. Calculate the total mass of compounds formed from 750 cm3 of sea water. mass = .............................. g

[1]
a(iii)

State which compound in Table 2.1 reacts with an acid to produce carbon dioxide.

[1]
b

Potassium bromide is found in sea water and contains bromide ions. Describe a test for bromide ions. test ............................................................................................................................................ ................................................................................................................................................... observations ............................................................................................................................. ...................................................................................................................................................

[2]
c

Calcium ions are in sea water. Complete Fig. 2.1 to show: • the electronic configuration of a calcium ion • the charge on the ion.

[2]
d

Sodium chloride is a solid at room temperature. Describe the arrangement and motion of the particles in a solid. arrangement ............................................................................................................................. ................................................................................................................................................... motion ....................................................................................................................................... ...................................................................................................................................................

[2]
e

Sea water contains dissolved nitrate ions. State one source of nitrate ions.

[1]
3

This question is about phosphorus and its compounds.

Figure 1 of 1 for question 3
a(i)

Phosphorus is in Group V of the Periodic Table. Explain why phosphorus is placed in this group.

[1]
a(ii)

Two isotopes of phosphorus are shown in Fig. 3.1. 1531P 1532P Fig. 3.1 Complete Table 3.1 to show the number of protons, neutrons and electrons in one atom of these isotopes. Table 3.1

protonsneutronselectrons
1531P
1532P
[3]
a(iii)

Phosphorus burns in oxygen to produce phosphorus(V) oxide. Complete the symbol equation for this reaction. .....P + .....O2→ P4O10

[2]
a(iv)

State whether phosphorus(V) oxide is an acidic oxide or a basic oxide. Give a reason for your answer.

[1]
b(i)

Phosphorus is one element in NPK fertilisers. Draw a circle around one other element that is also in NPK fertilisers. krypton nickel platinum potassium

[1]
b(ii)

State why farmers use fertilisers on fields where crops are grown.

[1]
c

A compound of phosphorus has the formula Ca3(PO4)2. Complete Table 3.2 to calculate the relative formula mass of Ca3(PO4)2. Table 3.2

atomnumber of atomsrelative atomic mass
oxygen8168×16=128
calcium40
phosphorus31

relative formula mass = ....................................

[2]
4

This question is about organic chemistry.

Figure 1 of 1 for question 4
a(i)

State the meaning of the term hydrocarbon.

[1]
a(ii)

Petroleum is a mixture of hydrocarbons. Outline how petroleum is separated into its useful components. Include in your answer: • the name of the separation technique • the property of the hydrocarbons which allows them to be separated • a description of how this technique separates the petroleum into its useful components.

[4]
a(iii)

Some of the products obtained from petroleum are shown. Draw a line from each product to its use. product: kerosene bitumen gasoline use: making roads fuel for cars jet fuel

[2]
b(i)

Ethanol is an organic molecule. Draw the displayed formula of a molecule of ethanol.

[2]
b(ii)

Ethanol is manufactured by the reaction of steam with ethene. State two conditions for this process. 1 ........................................................................................................................................ 2 ........................................................................................................................................

[2]
c(i)

Fig. 4.1 shows the displayed formula of tetramethylsilane. Deduce the molecular formula of tetramethylsilane.

[1]
c(ii)

Name the two elements in tetramethylsilane that are in the same group in the Periodic Table. ............................................................... and ...............................................................

[1]
5

This question is about zinc salts.

Figure 1 of 2 for question 5
Figure 2 of 2 for question 5
a(i)

Excess solid zinc oxide is added to dilute sulfuric acid to produce a salt. Complete the word equation for this reaction. zinc oxide + sulfuric acid → .......................... + .......................... ..........................

[2]
a(ii)

Name the method used to remove excess solid zinc oxide from the reaction mixture.

[1]
a(iii)

Describe how crystals of the pure salt are made from an aqueous solution of the salt formed.

[2]
b(i)

Fig. 5.1 shows the apparatus for the electrolysis of molten zinc chloride using inert electrodes. Label Fig. 5.1 to show the: • cathode • electrolyte.

[2]
b(ii)

Name a suitable material for the inert electrodes.

[1]
b(iii)

Name the products formed at the positive and negative electrodes. positive electrode .............................................................................................................. negative electrode .............................................................................................................

[2]
c

Zinc chloride has ionic bonds. State the meaning of the term ionic bond.

[2]
6

This question is about metals.

Figure 1 of 4 for question 6
Figure 2 of 4 for question 6
Figure 3 of 4 for question 6
Figure 4 of 4 for question 6
a(i)

A student investigates the reaction of four different metals, A, B, C and D, with dilute hydrochloric acid. All other conditions are the same in each test-tube. The results of the experiment are shown in Fig. 6.1. Put the metals, A, B, C and D, in order of their reactivity. most reactive ........................................... ........................................... ........................................... least reactive ...........................................

[1]
a(ii)

The student wants to decrease the rate of the reaction in the experiment. State two ways to decrease the rate of this reaction. 1 ........................................................................................................................................ 2 ........................................................................................................................................

[2]
b

In another experiment, a student adds potassium carbonate to dilute hydrochloric acid. State the colour seen in the flame test for potassium ions.

[1]
c(i)

Brass is a mixture of two metals. State the name given to a mixture of metals such as brass.

[1]
c(ii)

Name the two metals in brass. ............................................................... and ...............................................................

[2]
c(iii)

Magnalium is a mixture of magnesium and aluminium. Suggest one property of magnalium that makes it more useful than pure magnesium metal.

[1]
7
Figure 1 of 1 for question 7
a

Select two processes that show a chemical change. Tick (✓) two boxes. boiling water burning methane dissolving salt mixing ink and water rusting of iron

[2]
b

The reaction of hydrogen with nitrogen is a reversible reaction. Write the symbol that shows a reversible reaction.

[1]
c(i)

Table 7.1 shows the results of four experiments. Table 7.1

experimentinitial temperature/°Cfinal temperature/°C
11823
21917
31814
41929

State which experiment shows the greatest temperature change.

[1]
c(ii)

State which experiment is the most endothermic.

[1]
c(iii)

In experiment 4, magnesium was added to dilute hydrochloric acid. Complete the symbol equation. Mg + .....HCl → MgCl2 + ............

[2]
c(iv)

Fig. 7.1 shows an incomplete reaction pathway diagram for an endothermic reaction. Complete Fig. 7.1 by labelling: • the vertical axis • the reactants • the products.

[2]
8

This question is about water and air.

a

Water needs to be treated to make it safe to drink. Draw a line from each stage in the treatment of domestic water to the reason why it is carried out. stage: addition of carbon sedimentation chlorination reason: to kill microbes to remove tastes and odours to remove solids

[2]
b

Describe how to test whether a sample of water is pure using melting point.

[2]
c(i)

Air may contain sulfur dioxide and particulates. State one harmful effect of each of these air pollutants. sulfur dioxide ..................................................................................................................... particulates ........................................................................................................................

[2]
c(ii)

Describe how flue gas desulfurisation reduces emissions of sulfur dioxide gas.

[2]

Mark scheme

0620/32 · May/June 2025

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1a · 1 mark

  • 1 mark

    oxygen

1b · 1 mark

  • 1 mark

    magnesium oxide

1c · 1 mark

  • 1 mark

    iron

1d · 1 mark

  • 1 mark

    oxygen

1e · 1 mark

  • 1 mark

    carbon dioxide

1f · 1 mark

  • 1 mark

    potassium

1g · 1 mark

  • 1 mark

    sulfur dioxide

1h · 1 mark

  • 1 mark

    neon

1i · 1 mark

  • 1 mark

    bromine

2a(i) · 1 mark

  • 1 mark

    magnesium sulfate

2a(ii) · 1 mark

  • 1 mark

    18 / 18.0 (g)

2a(iii) · 1 mark

  • 1 mark

    calcium carbonate / CaCO3

2b · 2 marks

  • 1 mark

    test: (add nitric acid / acidify and add aqueous) silver nitrate

  • 1 mark

    observations: cream precipitate

2c · 2 marks

  • 1 mark

    electronic configuration 2,8,8 with no other shells added

  • 1 mark

    2+ / +2 outside brackets

2d · 2 marks

  • 1 mark

    arrangement: regular / in rows

  • 1 mark

    motion: vibrate

2e · 1 mark

  • 1 mark

    fertilisers

3a(i) · 1 mark

  • 1 mark

    Has 5 electrons in its outer shell

3a(ii) · 3 marks

  • 1 mark

    protons: 15 and 15

  • 1 mark

    neutrons: 16 and 17

  • 1 mark

    electrons: 15 and 15

3a(iii) · 2 marks

  • 1 mark

    4 (P)

  • 1 mark

    5 (O2)

3a(iv) · 1 mark

  • 1 mark

    acidic because phosphorus is a non-metal

3b(i) · 1 mark

  • 1 mark

    potassium

3b(ii) · 1 mark

  • 1 mark

    to increase crop growth / to replace elements taken from the soil by previous crops

3c · 2 marks

  • 1 mark

    Ca = (3 × 40) = 120 OR P = (2 × 31) = 62

  • 1 mark

    310

4a(i) · 1 mark

  • 1 mark

    compounds made up of carbon and hydrogen (atoms) only

4a(ii) · 4 marks

  • 1 mark

    separation technique: fractional distillation

  • 1 mark

    petroleum is heated / vapourised / evaporated

  • 1 mark

    fractionating column has a temperature gradient / column is hot at bottom and cold at top

  • 1 mark

    fractions condense (when they get to their boiling points)

  • 1 mark

    fractions are piped off as liquids

  • 1 mark

    property: have different boiling points

4a(iii) · 2 marks

  • 2 marks

    kerosene – jet fuel, bitumen – making roads, gasoline – fuel for cars (All 3 correct = 2 marks, 1 correct = 1 mark)

4b(i) · 2 marks

  • 2 marks

    whole molecule correct (displayed formula of ethanol)

4b(ii) · 2 marks

  • 1 mark

    high temperature / 300 (°C)

  • 1 mark

    high pressure / 6000 kPa / 60 atm

  • 1 mark

    acid catalyst

4c(i) · 1 mark

  • 1 mark

    SiC4H12

4c(ii) · 1 mark

  • 1 mark

    silicon and carbon

5a(i) · 2 marks

  • 1 mark

    zinc sulfate

  • 1 mark

    water

5a(ii) · 1 mark

  • 1 mark

    filtration

5a(iii) · 2 marks

  • 1 mark

    evaporate to point of crystallisation OR evaporate until saturated solution is formed OR heat until crystals just appear

  • 1 mark

    filter off crystals / pick out crystals

  • 1 mark

    dry with filter paper

5b(i) · 2 marks

  • 1 mark

    left hand electrode labelled cathode

  • 1 mark

    electrolyte labelled

5b(ii) · 1 mark

  • 1 mark

    graphite / carbon / platinum

5b(iii) · 2 marks

  • 1 mark

    positive electrode: chlorine

  • 1 mark

    negative electrode: zinc

5c · 2 marks

  • 1 mark

    electrostatic attraction

  • 1 mark

    between oppositely charged ions / between positive and negative ions

6a(i) · 1 mark

  • 1 mark

    most reactive – BCDA – least reactive

6a(ii) · 2 marks

  • 1 mark

    decrease temperature

  • 1 mark

    decrease concentration (of acid)

  • 1 mark

    decrease (surface) area of metal / larger pieces of metal

6b · 1 mark

  • 1 mark

    lilac

6c(i) · 1 mark

  • 1 mark

    alloy

6c(ii) · 2 marks

  • 1 mark

    copper

  • 1 mark

    zinc

6c(iii) · 1 mark

  • 1 mark

    harder / stronger

7a · 2 marks

  • 1 mark

    burning methane (second box down ticked)

  • 1 mark

    rusting of iron (fifth box down ticked)

7b · 1 mark

  • 1 mark

    ⇌

7c(i) · 1 mark

  • 1 mark

    (experiment) 4

7c(ii) · 1 mark

  • 1 mark

    (experiment) 3

7c(iii) · 2 marks

  • 1 mark

    2 (HCl)

  • 1 mark

    H2

7c(iv) · 2 marks

  • 1 mark

    energy (on the y-axis)

  • 1 mark

    reactants on left hand line and products on right hand line on the graph

8a · 2 marks

  • 2 marks

    addition of carbon – to remove tastes / odours, sedimentation – to remove solids, chlorination – to kill microbes (all 3 correct = 2 marks, 1 correct = 1 mark)

8b · 2 marks

  • 1 mark

    heat to melting point of the sample and measure mp OR heat to 0 °C and observe if it’s melting

  • 1 mark

    pure water melts at 0 °C / has a sharp melting point / if not 0°C then it must be impure. OR impure water melts at a lower mp than 0 °C / melts over a range of temperatures OR compare the melting point of the water sample to the mp of pure water.

8c(i) · 2 marks

  • 1 mark

    sulfur dioxide: acid rain

  • 1 mark

    particulates: respiratory problems / cancer

8c(ii) · 2 marks

  • 1 mark

    calcium oxide

  • 1 mark

    neutralisation

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  3. 3
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