IGCSE Chemistry 0620 Paper 33, May/June 2025

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Question paper

0620/33 · May/June 2025

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1

A list of substances is shown. calcium calcium oxide carbon carbon dioxide chlorine copper gold iodine neon nitrogen oxygen potassium sulfur dioxide Answer the following questions about these substances. Each substance may be used once, more than once or not at all. State which substance is:

a

an element which forms an ion with a 3– charge

[1]
b

a transition element

[1]
c

a gas that is identified using limewater

[1]
d

approximately 78% of clean, dry air

[1]
e

used in electrical wiring

[1]
f

the least reactive metal in the list

[1]
g

a diatomic molecule which is a solid at room temperature and pressure

[1]
h

a compound that reacts with impurities in the blast furnace to form slag

[1]
i

an element with a relative atomic mass of 12.

[1]
2

This question is about sea water and the substances found in sea water.

Figure 1 of 2 for question 2
Figure 2 of 2 for question 2
a(i)

Table 2.1 shows the masses of the compounds present when a 2000 cm3 sample of sea water is evaporated. Table 2.1 Answer these questions using the information from Table 2.1. State the chemical name of MgSO4.

[1]
a(ii)

The total mass of compounds formed from 2000 cm3 of sea water is 38.0 g. Calculate the total mass of compounds present in 800 cm3 of sea water. mass = .............................. g

[1]
a(iii)

Potassium chloride is soluble in water. Choose one other compound that is soluble in water. Tick (✓) one box. lead(II) sulfate magnesium carbonate silver chloride sodium hydroxide

[1]
b

Potassium iodide is also found in sea water and contains iodide ions. Describe a test for iodide ions. test ............................................................................................................................................ observations .............................................................................................................................

[2]
c

Potassium chloride contains potassium ions. Complete Fig. 2.1 to show: • the electronic configuration of a potassium ion • the charge on the ion.

[2]
d

Sodium chloride is a solid at room temperature. Describe the separation and motion of the particles in a solid. separation ................................................................................................................................. motion .......................................................................................................................................

[2]
e

Sea water contains dissolved phosphate ions. State one source of phosphate ions.

[1]
f

Water is a simple molecular compound. Complete the dot-and-cross diagram in Fig. 2.2 for a molecule of water. Show outer electrons only.

[2]
3

This question is about organic chemistry.

Figure 1 of 1 for question 3
a(i)

Petroleum is a mixture of hydrocarbons and is separated by fractional distillation in an industrial process. State which physical property of hydrocarbons allows them to be separated by fractional distillation.

[1]
a(ii)

Describe how petroleum is separated into fractions by fractional distillation.

[2]
a(iii)

Name the process that breaks down long chain hydrocarbon molecules to form short chain hydrocarbon molecules.

[1]
a(iv)

Some of the fractions obtained from petroleum are shown. Draw a line from each fraction to its use.

[2]
b(i)

Ethanoic acid is an organic molecule. Draw the displayed formula of a molecule of ethanoic acid.

[2]
b(ii)

Ethanoic acid reacts with sodium carbonate. Name the salt produced in this reaction.

[1]
c

Ethane is burned in excess oxygen. Name the two products of this process. ................................................................... and ...................................................................

[2]
d

Ethanol is another organic molecule. State two ways to manufacture ethanol. 1 ................................................................................................................................................ 2 ................................................................................................................................................

[2]
e(i)

Fig. 3.1 shows the displayed formula of an organic molecule. Deduce the molecular formula of the molecule in Fig. 3.1.

[1]
e(ii)

Explain why the molecule in Fig. 3.1 is unsaturated.

[1]
4

This question is about nitrogen and its compounds.

Figure 1 of 1 for question 4
a(i)

Explain why nitrogen is in Group V of the Periodic Table.

[1]
a(ii)

Two isotopes of nitrogen are shown in Fig. 4.1. 714N 715N Fig. 4.1 Complete Table 4.1 to show the number of protons, neutrons and electrons in one atom of these isotopes.

[3]
b(i)

Oxides of nitrogen are air pollutants. State one source of oxides of nitrogen in the air.

[1]
b(ii)

Ammonia reacts with oxygen to form nitrogen dioxide and water. Complete the symbol equation for this reaction. 4NH3+7O2→4NO2+.....H2O

[1]
b(iii)

State the type of bonding between the atoms in nitrogen dioxide.

[1]
b(iv)

State whether nitrogen dioxide is an acidic or basic oxide. Give a reason for your answer.

[1]
c

A compound of nitrogen has the formula Al(NO3)3. Complete Table 4.2 to calculate the relative formula mass of Al(NO3)3. Table 4.2 relative formula mass = ..............................

[2]
5

This question is about ionic compounds and simple molecular compounds.

Figure 1 of 2 for question 5
Figure 2 of 2 for question 5
a

Complete the word equation to show the reaction between copper(II) carbonate and nitric acid.

[3]
b

Aqueous magnesium chloride is prepared by adding excess magnesium oxide powder to dilute hydrochloric acid. Describe how to prepare a sample of pure, dry magnesium chloride crystals after the reaction is complete. In your answer describe how to: • remove the excess magnesium oxide from the reaction mixture • crystallise the magnesium chloride • dry the crystals.

[3]
c(i)

Fig. 5.1 shows the apparatus for the electrolysis of molten cobalt(II) bromide using inert electrodes. Label Fig. 5.1 to show the: • anode • electrolyte.

[2]
c(ii)

Name the products formed at the positive and negative electrodes. positive electrode .............................................................................................................. negative electrode .............................................................................................................

[2]
d

Table 5.1 shows some properties of five compounds, A, B, C, D and E. Table 5.1 State which two of the compounds, A, B, C, D and E, are simple molecules. Give two reasons for your answer. compounds ............................................................ and ............................................................ reason 1 ..................................................................................................................................... reason 2 ....................................................................................................................................

[3]
6

This question is about chemical reactions and their energy changes.

Figure 1 of 1 for question 6
a

Tick (✓) one box that shows a chemical change. boiling ethanol decomposing vegetation dissolving salt mixing ink and water

[1]
b(i)

Table 6.1 shows the results of four experiments. Table 6.1 State which experiment shows the greatest temperature change.

[1]
b(ii)

State which experiment is the most endothermic.

[1]
b(iii)

Fig. 6.1 shows an incomplete reaction pathway diagram for an exothermic reaction. Complete Fig. 6.1 by labelling: • the vertical axis • the reactants • the products.

[2]
7

This question is about air and water.

Figure 1 of 1 for question 7
a

Water needs to be treated to make it safe to drink. Complete Fig. 7.1 to show the three stages needed in the treatment of domestic water. The second stage has been completed.

[2]
b

Describe a chemical test for the presence of water. test ............................................................................................................................................ observations .............................................................................................................................

[2]
c

A sample of air contains carbon dioxide and oxides of nitrogen. State one harmful effect of each of these air pollutants. carbon dioxide .......................................................................................................................... oxides of nitrogen .....................................................................................................................

[2]
8

This question is about metals.

Figure 1 of 4 for question 8
Figure 2 of 4 for question 8
Figure 3 of 4 for question 8
Figure 4 of 4 for question 8
a(i)

A student investigates the reaction of four different metals, A, B, C and D, with dilute sulfuric acid. All other conditions are the same. The results of the experiments are shown in Table 8.1. Table 8.1 Put the metals, A, B, C and D, in order of their reactivity. most reactive .............................. .............................. .............................. least reactive ..............................

[1]
a(ii)

Increasing the temperature of the acid increases the rate of reaction. State two other ways to increase the rate of this reaction. 1 ........................................................................................................................................ 2 ........................................................................................................................................

[2]
b(i)

In another experiment, a student adds lithium to water. An alkaline solution is formed. State the colour seen in the flame test for lithium ions.

[1]
b(ii)

State the ion that all aqueous alkalis contain.

[1]
b(iii)

State the colour of thymolphthalein in an aqueous alkali.

[1]
c(i)

Pewter is an alloy that contains tin. State which one of these diagrams, A, B, C or D, best represents an alloy.

[1]
c(ii)

Suggest one property of pewter that makes it more useful than pure tin.

[1]
d

Metals are good thermal conductors. Describe two other physical properties that are typical of metals. 1 ................................................................................................................................................ 2 ................................................................................................................................................

[2]

Mark scheme

0620/33 · May/June 2025

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1a · 1 mark

  • 1 mark

    nitrogen

1b · 1 mark

  • 1 mark

    copper or gold

1c · 1 mark

  • 1 mark

    carbon dioxide

1d · 1 mark

  • 1 mark

    nitrogen

1e · 1 mark

  • 1 mark

    copper

1f · 1 mark

  • 1 mark

    gold

1g · 1 mark

  • 1 mark

    iodine

1h · 1 mark

  • 1 mark

    calcium oxide

1i · 1 mark

  • 1 mark

    carbon

2a(i) · 1 mark

  • 1 mark

    magnesium sulfate

2a(ii) · 1 mark

  • 1 mark

    15.2 (g)

2a(iii) · 1 mark

  • 1 mark

    4th box down ticked (sodium hydroxide)

2b · 2 marks

  • 1 mark

    test: (add nitric acid / acidify and add aqueous) silver nitrate

  • 1 mark

    observations: (pale) yellow precipitate

2c · 2 marks

  • 1 mark

    electronic configuration 2,8,8 with no other shells added

  • 1 mark

    1+ / + outside brackets

2d · 2 marks

  • 1 mark

    separation: (very) close / touching

  • 1 mark

    motion: vibrate

2e · 1 mark

  • 1 mark

    fertilisers / detergents

2f · 2 marks

  • 1 mark

    pair of electrons between each H and O and no other electrons on H

  • 1 mark

    4 non-bonding electrons on O

3a(i) · 1 mark

  • 1 mark

    different boiling points

3a(ii) · 2 marks

  • 1 mark

    petroleum is heated / vapourised / evaporated

  • 1 mark

    fractionating column has a temperature gradient / column is hot at bottom and cold at top

  • 1 mark

    fractions condense (when they get to their boiling points)

  • 1 mark

    fractions are piped off as liquids

3a(iii) · 1 mark

  • 1 mark

    cracking

3a(iv) · 2 marks

  • 2 marks

    bitumen – making roads lubricating oil – waxes and polishes naphtha – chemical feedstock

3b(i) · 2 marks

  • 2 marks

    displayed formula of ethanoic acid with all bonds shown correctly

3b(ii) · 1 mark

  • 1 mark

    sodium ethanoate

3c · 2 marks

  • 1 mark

    carbon dioxide

  • 1 mark

    water

3d · 2 marks

  • 1 mark

    Fermentation

  • 1 mark

    (catalytic addition of) steam to ethene

3e(i) · 1 mark

  • 1 mark

    C7H12O4

3e(ii) · 1 mark

  • 1 mark

    has a C=C bond / has a carbon-carbon double bond

4a(i) · 1 mark

  • 1 mark

    has 5 electrons in its outer shell

4a(ii) · 3 marks

  • 1 mark

    protons column: 7 and 7

  • 1 mark

    neutrons column: 7 and 8

  • 1 mark

    electrons column: 7 and 7

4b(i) · 1 mark

  • 1 mark

    car engines

4b(ii) · 1 mark

  • 1 mark

    6 (H2O)

4b(iii) · 1 mark

  • 1 mark

    covalent

4b(iv) · 1 mark

  • 1 mark

    acidic because nitrogen is a non-metal

4c · 2 marks

  • 1 mark

    Al = (1 × 27) = 27 OR N = (3 × 14) = 42

  • 1 mark

    213

5a · 3 marks

  • 1 mark

    copper nitrate

  • 1 mark

    carbon dioxide

  • 1 mark

    water

5b · 3 marks

  • 1 mark

    filtration / filter (off the excess magnesium oxide)

  • 1 mark

    evaporate to point of crystallisation OR evaporate until saturated solution is formed OR heat until crystals just appear

  • 1 mark

    dry with (filter) paper

5c(i) · 2 marks

  • 1 mark

    right hand electrode labelled anode

  • 1 mark

    electrolyte labelled

5c(ii) · 2 marks

  • 1 mark

    positive electrode: bromine

  • 1 mark

    negative electrode: cobalt

5d · 3 marks

  • 1 mark

    C and E

  • 1 mark

    low melting point

  • 1 mark

    does not conduct electricity (when molten)

6a · 1 mark

  • 1 mark

    decomposing vegetation (second box down ticked).

6b(i) · 1 mark

  • 1 mark

    Experiment 2

6b(ii) · 1 mark

  • 1 mark

    Experiment 1

6b(iii) · 2 marks

  • 1 mark

    label on y-axis – energy

  • 1 mark

    reactants on left hand line and products on right hand line on the graph

7a · 2 marks

  • 1 mark

    sedimentation / filtration

  • 1 mark

    chlorination / adding chlorine

7b · 2 marks

  • 1 mark

    test: (anhydrous) copper(II) sulfate / (anhydrous) cobalt(II) chloride

  • 1 mark

    observations: white to blue / blue to pink

7c · 2 marks

  • 1 mark

    carbon dioxide: global warming / climate change

  • 1 mark

    oxides of nitrogen: acid rain / photochemical smog / respiratory problems

8a(i) · 1 mark

  • 1 mark

    most reactive – ADCB – least reactive

8a(ii) · 2 marks

  • 1 mark

    increase the concentration (of the acid)

  • 1 mark

    add a catalyst

  • 1 mark

    increase (surface) area of metal / smaller pieces of metal

8b(i) · 1 mark

  • 1 mark

    red

8b(ii) · 1 mark

  • 1 mark

    OH‾

8b(iii) · 1 mark

  • 1 mark

    blue

8c(i) · 1 mark

  • 1 mark

    D

8c(ii) · 1 mark

  • 1 mark

    harder / stronger

8d · 2 marks

  • 1 mark

    malleable

  • 1 mark

    ductile

  • 1 mark

    good electrical conductor

  • 1 mark

    high melting point / high boiling point

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  3. 3
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  4. 4
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  5. 5
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  6. 6
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